3-苯胺基-2-环己烯-1-酮 ,3-Anilino-2-cyclohexen-1-one

产品编号:SIGMA-TMT00599| CAS NO:24706-50-1| 分子式:C12H13NO| 分子量:187.2377

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SIGMA-TMT00599
6541.00 杭州 北京(现货)

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产品名称 3-苯胺基-2-环己烯-1-酮
英文名称3-Anilino-2-cyclohexen-1-one
CAS编号24706-50-1
产品熔点178-182 °C
产品沸点324.9ºC at 760mmHg
产品密度1.176g/cm3
产品闪点135.6ºC
精确质量187.10000
PSA29.10000
LogP2.80840
蒸气压0.000238mmHg at 25°C
折射率1.629
稳定性

如果遵照规格使用和储存则不会分解

避免接触氧化物
储存条件

保持贮藏器密封

放入紧密的贮藏器内,储存在阴凉,干燥的地方

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危害码 (欧洲) Xi: Irritant;
风险声明 (欧洲) R36/37/38
安全声明 (欧洲) S24/25
RTECS号 GW7600000
海关编码 2922399090
Name: 3-(Phenylamino)cyclohex-2-ene-1-one 98% Material Safety Data Sheet
Synonym:
CAS: 24706-50-1
Section 1 - Chemical Product MSDS Name:3-(Phenylamino)cyclohex-2-ene-1-one 98% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
24706-50-1 3-(Phenylamino)cyclohex-2-ene-1-one 98% unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 24706-50-1: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Crystalline powder
Color: yellow-green - fine
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 178 - 182 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density:
Molecular Formula: C12H13NO
Molecular Weight: 187.24

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 24706-50-1: GW7600000 LD50/LC50:
Not available.
Carcinogenicity:
3-(Phenylamino)cyclohex-2-ene-1-one - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 24706-50-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 24706-50-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 24706-50-1 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

~96%

24706-50-1结构式

24706-50-1

文献:Epifano, Francesco; Genovese, Salvatore; Curini, Massimo Tetrahedron Letters, 2007 , vol. 48, # 15 p. 2717 - 2720

~93%

24706-50-1结构式

24706-50-1

文献:Merck and Co., Inc. Patent: EP214009 A3, 1989 ;

~89%

24706-50-1结构式

24706-50-1

文献:Zhuo, Jin-Cong Magnetic Resonance in Chemistry, 1997 , vol. 35, # 5 p. 311 - 322

~78%

24706-50-1结构式

24706-50-1

文献:Bergman, Jan; Stensland, Birgitta Journal of Heterocyclic Chemistry, 2014 , vol. 51, # 1 p. 1 - 10

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