1-苄基-4-羟基哌啶 ,1-Benzyl-4-hydroxypiperidine ,96%

产品编号:SIGMA-152986| CAS NO:4727-72-4| 分子式:C12H18NO| 分子量:192.2769

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SIGMA-152986
807.00 杭州 北京(现货)

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产品名称 1-苄基-4-羟基哌啶
英文名称1-Benzyl-4-hydroxypiperidine
CAS编号4727-72-4
产品熔点61-63 °C(lit.)
产品沸点294.4±0.0 °C at 760 mmHg
产品密度1.1±0.1 g/cm3
产品闪点123.5±16.5 °C
精确质量191.131012
PSA23.47000
LogP0.91
外观性状淡黄色晶体
蒸气压0.0±0.6 mmHg at 25°C
折射率1.578
稳定性

常温常压下稳定,浅黄色晶体,可溶于水

储存条件

常温,避光,通风干燥处,密封保存

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符号 GHS06
GHS06
信号词 Danger
危害声明 H301-H315-H319-H335
警示性声明 P261-P301 + P310-P305 + P351 + P338
个人防护装备 Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges
危害码 (欧洲) T:Toxic
风险声明 (欧洲) R25;R36/37/38
安全声明 (欧洲) S26-S45-S37/39
危险品运输编码 UN 2811 6.1/PG 3
WGK德国 2
海关编码 2933399090
Name: 1-Benzyl-4-Hydroxypiperidine 97% Material Safety Data Sheet
Synonym: 1-Benzyl-4-Piperidino
CAS: 4727-72-4
Section 1 - Chemical Product MSDS Name:1-Benzyl-4-Hydroxypiperidine 97% Material Safety Data Sheet
Synonym:1-Benzyl-4-Piperidino

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
4727-72-4 1-Benzyl-4-Hydroxypiperidine 97% 225-226-9
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Hygroscopic (absorbs moisture from the air).The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical aid. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Keep container closed when not in use.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits CAS# 4727-72-4: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Crystals
Color: light yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 127.0 -128.0 deg C @ 2.00mmHg
Freezing/Melting Point: 61.00 - 63.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C12H17NO
Molecular Weight: 191.27

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, strong oxidants, heat.
Incompatibilities with Other Materials:
Strong oxidizing agents - moisture - strong acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 4727-72-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-Benzyl-4-Hydroxypiperidine - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 4727-72-4: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 4727-72-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 4727-72-4 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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