氧化铋 ,Bismuth oxide ,99.8% trace metals b

产品编号:SIGMA-637017| CAS NO:1304-76-3| 分子式:Bi4O6| 分子量:931.918

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货号 包装 价格 库存与货期 购买量 操作
SIGMA-637017
1153.00 杭州 北京(现货)
SIGMA-637017
529.00 杭州 北京(现货)
SIGMA-637017
1780.00 杭州 北京(现货)
SIGMA-637017
1606.00 杭州 北京(现货)
SIGMA-637017
3354.00 杭州 北京(现货)

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产品名称 氧化铋
英文名称Bismuth oxide
CAS编号1304-76-3
产品熔点825 °C
产品沸点1890°C
产品密度8.9
产品闪点1890°C
精确质量465.945557
外观性状黄色粉末
溶解性INSOLUBLE
稳定性

1.如果遵照规格使用和储存则不会分解,未有已知危险反应,避免氧化物。

2.三氧化二铋纯品有α型和β型。α型为黄色单斜晶系结晶,相对密度8.9,熔点825 ℃,溶于酸,不溶于水和碱。β型为亮黄色至橙色,正方晶系,相对密度8.55,熔点860 ℃,溶于酸,不溶于水。容易被氢气、烃类等还原为金属铋。

储存条件

保持贮藏器密封、储存在阴凉、干燥的地方,确保工作间有良好的通风或排气装置。

相关文档

化学品安全说明书(MSDS)

下载MSDS

质检证书(COA)

相关产品


个人防护装备 dust mask type N95 (US);Eyeshields;Gloves
危害码 (欧洲) Xi: Irritant;
风险声明 (欧洲) R36/37/38
安全声明 (欧洲) S26-S36/37
危险品运输编码 NONH for all modes of transport
WGK德国 2
RTECS号 EB2984460
海关编码 8106009090
Name: Bismuth(III) oxide Material Safety Data Sheet
Synonym: Bismuth trioxide; Bismuthous oxide; Bismuth yellow
CAS: 1304-76-3
Section 1 - Chemical Product MSDS Name:Bismuth(III) oxide Material Safety Data Sheet
Synonym:Bismuth trioxide; Bismuthous oxide; Bismuth yellow

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
1304-76-3 Bismuth trioxide >99 215-134-7
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. May cause liver and kidney damage.
Inhalation:
May cause respiratory tract irritation.
Chronic:
May cause liver and kidney damage.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion:
Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 1304-76-3: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: yellow
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 825 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: practically insoluble in water.
Specific Gravity/Density: 8.8
Molecular Formula: Bi2O3
Molecular Weight: 465.96

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation.
Incompatibilities with Other Materials:
No significant incompatibilities identified with common materials and contaminants..
Hazardous Decomposition Products:
None.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 1304-76-3: EB2984460 LD50/LC50:
CAS# 1304-76-3: Oral, mouse: LD50 = 10 gm/kg; Oral, rat: LD50 = 5000 mg/kg.
Carcinogenicity:
Bismuth trioxide - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 1304-76-3: 1
Canada
CAS# 1304-76-3 is listed on Canada's DSL List.
CAS# 1304-76-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1304-76-3 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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