草酰溴 ,Oxalyl bromide ,97%

产品编号:SIGMA-113034| CAS NO:15219-34-8| 分子式:C2Br2O2| 分子量:215.8282

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货号 包装 价格 库存与货期 购买量 操作
SIGMA-113034
1581.00 杭州 北京(现货)
SIGMA-113034
3416.00 杭州 北京(现货)
SIGMA-113034
1382.00 杭州 北京(现货)
SIGMA-113034
6942.00 杭州 北京(现货)

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产品名称 草酰溴
英文名称Oxalyl bromide
CAS编号15219-34-8
产品熔点-19ºC
产品沸点118.3±0.0 °C at 760 mmHg
产品密度2.6±0.1 g/cm3
产品闪点109.8±9.2 °C
精确质量213.826492
PSA34.14000
LogP1.41
外观性状透明液体
蒸气压16.8±0.2 mmHg at 25°C
折射率1.567
稳定性

遵照规定使用和储存则不会分解。

储存条件

密闭于4 ºC阴凉干燥环境中

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符号 GHS05 GHS07
GHS05, GHS07
信号词 Danger
危害声明 H314-H332
补充危害声明 Contact with water liberates toxic gas., Reacts violently with water.
警示性声明 P280-P305 + P351 + P338-P310
个人防护装备 Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
危害码 (欧洲) C
风险声明 (欧洲) R23/24/25
安全声明 (欧洲) 26-36/37/39-45-28-27
危险品运输编码 UN 2922 8/PG 1
WGK德国 3
包装等级 II
海关编码 2917190090
Name: Oxalyl bromide 98% Material Safety Data Sheet
Synonym:
CAS: 15219-34-8
Section 1 - Chemical Product MSDS Name:Oxalyl bromide 98% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
15219-34-8 OXALYL BROMIDE 239-271-7
Hazard Symbols: C
Risk Phrases: 34

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Causes burns.The toxicological properties of this material have not been fully investigated.Cancer suspect agent.Light sensitive.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow of tears).
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns. The toxicological properties of this substance have not been fully investigated.
Inhalation:
Causes chemical burns to the respiratory tract. The toxicological properties of this substance have not been fully investigated.
Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Do NOT use water directly on fire. Use carbon dioxide or dry chemical.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

Section 7 - HANDLING and STORAGE
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage:
Do not store in direct sunlight. Store in a tightly closed container. Store in a dry area. Keep under a nitrogen blanket. Keep refrigerated. (Store below 4C/39F.)

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 15219-34-8: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: clear golden
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 102 - 103 deg C @ 720.00mm Hg
Freezing/Melting Point: -19 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: reacts with water
Specific Gravity/Density:
Molecular Formula: C2Br2O2
Molecular Weight: 215.83

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, light, exposure to moist air or water.
Incompatibilities with Other Materials:
Bases, oxidizing agents, alcohol, steel.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 15219-34-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
OXALYL BROMIDE - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: CORROSIVE LIQUID, N.O.S.*
Hazard Class: 8
UN Number: 1760
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing group: II

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 15219-34-8: No information available.
Canada
CAS# 15219-34-8 is listed on Canada's NDSL List.
CAS# 15219-34-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 15219-34-8 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

~82%

15219-34-8结构式

15219-34-8

文献:Schmidt, Arthur H.; Russ, Manuel; Grosse, Detlef Synthesis, 1981 , # 3 p. 216 - 218

~%

15219-34-8结构式

15219-34-8

文献:Chemische Berichte, , vol. 46, p. 1435

~%

15219-34-8结构式

15219-34-8

文献:Chemische Berichte, , vol. 45, p. 1594

~%

15219-34-8结构式

15219-34-8

详细
文献:American Chemical Journal, , vol. 36, p. 493

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