二乙氨基乙醇 ,N,N-Diethylethanolamine ,≥99.5%

产品编号:SIGMA-471321| CAS NO:100-37-8| 分子式:C6H15NO| 分子量:117.1894

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货号 包装 价格 库存与货期 购买量 操作
SIGMA-471321
300.00 杭州 北京(现货)
SIGMA-471321
383.00 杭州 北京(现货)
SIGMA-471321
1036.00 杭州 北京(现货)
SIGMA-471321
7392.00 杭州 北京(现货)
SIGMA-471321
282.00 杭州 北京(现货)

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产品名称 二乙氨基乙醇
英文名称N,N-Diethylethanolamine
CAS编号100-37-8
产品熔点-70 °C
产品沸点164.8±13.0 °C at 760 mmHg
产品密度0.9±0.1 g/cm3
产品闪点48.9±0.0 °C
精确质量117.115364
PSA23.47000
LogP0.74
外观性状透明至淡黄色液体
蒸气压0.7±0.7 mmHg at 25°C
折射率1.443
溶解性soluble
稳定性

1.化学性质:具有叔胺和醇的化学反应性。用过氧化氢、高锰酸钾等氧化时,生成乙醇、乙酸、乙酰氧肟酸、氨、乙二醛和草酸等。用四乙酸铅氧化时,生成二乙胺与乙二醇醛。用硫代硫酸钾室温氧化生成乙醛。并可形成盐酸盐C6H15NO·HCl(熔点135~136℃),苦味酸盐[C6H15NO·C6H3N3O7(熔点79℃)]。

2.稳定性 稳定

3.禁配物 强氧化剂、强酸

4.聚合危害 不聚合

储存条件

储存注意事项储存于阴凉、通风的库房。库温不宜超过37℃。远离火种、热源。保持容器密封。应与氧化剂、酸类、食用化学品分开存放,切忌混储。采用防爆型照明、通风设施。禁止使用易产生火花的机械设备和工具。储区应备有泄漏应急处理设备和合适的收容材料。

相关文档

化学品安全说明书(MSDS)

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质检证书(COA)

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符号 GHS02 GHS05 GHS06
GHS02, GHS05, GHS06
信号词 Danger
危害声明 H226-H302-H311 + H331-H314
警示性声明 P210-P280-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338-P370 + P378
个人防护装备 Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
危害码 (欧洲) C:Corrosive
风险声明 (欧洲) R10;R20/21/22;R34
安全声明 (欧洲) S25-S26-S36/37/39-S45
危险品运输编码 UN 2686 8/PG 2
WGK德国 1
RTECS号 KK5075000
包装等级 II
危险类别 8
海关编码 2922192210
Name: N N-Diethylethanolamine P.A. Material Safety Data Sheet
Synonym: 2-Diethylaminoethanol, Beta-Diethylaminoethano
CAS: 100-37-8
Section 1 - Chemical Product MSDS Name:N N-Diethylethanolamine P.A. Material Safety Data Sheet
Synonym:2-Diethylaminoethanol, Beta-Diethylaminoethano

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
100-37-8 N,N-Diethylethanolamine 99.0 202-845-2
Hazard Symbols: XI
Risk Phrases: 10 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Flammable. Irritating to eyes, respiratory system and skin.Hygroscopic.
Potential Health Effects
Eye:
May cause eye irritation. May cause eye injury.
Skin:
May cause severe skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
Vapors may cause dizziness or suffocation. May cause nausea and possible vomiting.
Chronic:
None

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Antidote: None reported.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Do NOT get water inside containers. For large fires, use water spray, fog or alcohol-resistant foam. Cool containers with flooding quantities of water until well after fire is out.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Use water spray to disperse the gas/vapor. Remove all sources of ignition. Use a spark-proof tool.
Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame.
Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. Store protected from moisture.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Appearance: clear yellow brown
Odor: unpleasant odor
pH: Not available.
Vapor Pressure: 1.9 mbar @ 20 C
Viscosity: 5mPa @ 20C
Boiling Point: 161 deg C @ 760.00mm Hg
Freezing/Melting Point: -70 deg C
Autoignition Temperature: 260 deg C ( 500.00 deg F)
Flash Point: 60 deg C ( 140.00 deg F)
Explosion Limits, lower: 6.70 vol %
Explosion Limits, upper: 11.7 vol %
Decomposition Temperature:
Solubility in water: soluble
Specific Gravity/Density: .8840g/cm3
Molecular Formula: C6H15NO
Molecular Weight: 117.19

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong oxidants, exposure to moist air or water.
Incompatibilities with Other Materials:
Moisture.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 100-37-8: KK5075000 LD50/LC50:
CAS# 100-37-8: Dermal, guinea pig: LD50 = 1 mL/kg; Draize test, rabbit, eye: 5 mg Severe; Inhalation, mouse: LC50 = 5000 mg/m3; Oral, rat: LD50 = 1300 mg/kg; Skin, rabbit: LD50 = 1260 uL/kg.
Carcinogenicity:
N,N-Diethylethanolamine - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Fish: Fathead Minnow: 1780 mg/L; 96 Hr.; Flow-through

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: 2-DIETHYLAMINOETHANOL
Hazard Class: 8
UN Number: 2686
Packing Group: II
IMO
Shipping Name: DIETHYLAMINOETHANOL
Hazard Class: 3.3
UN Number: 2686
Packing Group: III
RID/ADR
Shipping Name: DIETHYLAMINOETHANOL
Dangerous Goods Code: 3(31C)
UN Number: 2686

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 10 Flammable.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 100-37-8: 1
United Kingdom Occupational Exposure Limits
CAS# 100-37-8: OES-United Kingdom, TWA 10 ppm TWA; 49 mg/m3 TWA
Canada
CAS# 100-37-8 is listed on Canada's DSL List.
CAS# 100-37-8 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 100-37-8: OEL-AUSTRALIA:TWA 10 ppm (50 mg/m3);Skin
OEL-AUSTRIA:TWA 10 ppm (50 mg/m3);Skin
OEL-BELGIUM:TWA 10 ppm (48 mg/m3);Skin
OEL-DENMARK:TWA 10 ppm (50 mg/m3);Skin
OEL-FINLAND:STEL 10 ppm (50 mg/m3);Skin
OEL-FRANCE:TWA 10 ppm (50 mg/m3);Skin
OEL-GERMANY:TWA 10 ppm (50 mg/m3);Skin
OEL-THE NETHERLANDS:TWA 10 ppm (50 mg/m3);Skin
OEL-THE PHILIPPINES:TWA 10 ppm (50 mg/m3);Skin
OEL-RUSSIA:STEL 5 mg/m3;Skin
OEL-SWITZERLAND:TWA 10 ppm (50 mg/m3);Skin
OEL-UNITED KINGDOM:TWA 10 ppm (50 mg/m3);Skin
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 100-37-8 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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