(+)-1,2-双[(2S,5S)-2,5-二甲基磷]苯 |1,2-Bis[(2S,5S)-2,5-dimethyl-1-phospholanyl]benzene |cas:136735-95-0|西域试剂

(+)-1,2-双[(2S,5S)-2,5-二甲基磷]苯 ,1,2-Bis[(2S,5S)-2,5-dimethyl-1-phospholanyl]benzene

产品编号：SIGMA-665266| CAS NO：136735-95-0| 分子式：C18H28P2| 分子量：306.3624

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货号	包装	价格	库存与货期	购买量	操作
SIGMA-665266		￥638.00	杭州北京（现货）
SIGMA-665266		￥2792.00	杭州北京（现货）

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产品名称	(+)-1,2-双[(2S,5S)-2,5-二甲基磷]苯
英文名称	1,2-Bis[(2S,5S)-2,5-dimethyl-1-phospholanyl]benzene
CAS编号	136735-95-0
产品熔点	67-76ºC
产品沸点	415ºC at 760 mmHg
产品闪点	216.3ºC
精确质量	306.16700
PSA	27.18000
LogP	5.04260
蒸气压	1.03E-06mmHg at 25°C
稳定性	如果遵照规格使用和储存则不会分解，未有已知危险反应
储存条件	保持贮藏器密封、储存在阴凉、干燥的地方，确保工作间有良好的通风或排气装置

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个人防护装备	Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
危害码 (欧洲)	Xi
风险声明 (欧洲)	R36/37/38
安全声明 (欧洲)	S26
危险品运输编码	NONH for all modes of transport

Name:	(+)-1 2-Bis((2S 5S)-2 5-dimethylphospholano)benzene Material Safety Data Sheet
Synonym:	(S,S)-Me-DUPHOS
CAS:	136735-95-0

Section 1 - Chemical Product MSDS Name:(+)-1 2-Bis((2S 5S)-2 5-dimethylphospholano)benzene Material Safety Data Sheet
Synonym:(S,S)-Me-DUPHOS

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
136735-95-0	(+)-1,2-Bis((2S,5S)-2,5-dimethylphosph		unlisted

Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
Air sensitive.Moisture sensitive.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Store under nitrogen.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 136735-95-0: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Crystals
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density:
Molecular Formula: C18H28P2
Molecular Weight: 306.37

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Exposure to air, exposure to moist air or water.
Incompatibilities with Other Materials:
Oxidizing agents, halogens.
Hazardous Decomposition Products:
Carbon monoxide, oxides of phosphorus, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 136735-95-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
(+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 136735-95-0: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 136735-95-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 136735-95-0 is not listed on the TSCA inventory.
It is for research and development use only.

SECTION 16 - ADDITIONAL INFORMATION
N/A