1-氨基-4-溴-2-甲基蒽醌 ,0.99 ,99%

产品编号:SIGMA-246697| CAS NO:81-50-5| 分子式:C15H10BrNO2| 分子量:316.15

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货号 包装 价格 库存与货期 购买量 操作
SIGMA-246697
751.00 杭州 北京(现货)

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产品名称 1-氨基-4-溴-2-甲基蒽醌
英文名称0.99
CAS编号81-50-5
产品熔点245ºC (dec.)(lit.)
产品沸点526.5±50.0 °C at 760 mmHg
产品密度1.6±0.1 g/cm3
产品闪点272.2±30.1 °C
精确质量314.989471
PSA60.16000
LogP4.93
外观性状橙色至红色结晶粉末
蒸气压0.0±1.4 mmHg at 25°C
折射率1.706
稳定性

与强氧化剂,强酸反应。

储存条件

密封贮藏,储存在阴凉、干燥地方。

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符号 GHS07
GHS07
信号词 Warning
危害声明 H315-H319-H335
警示性声明 P261-P305 + P351 + P338
个人防护装备 dust mask type N95 (US);Eyeshields;Gloves
危害码 (欧洲) Xi: Irritant;
风险声明 (欧洲) 36/37/38
安全声明 (欧洲) 26-37/39
危险品运输编码 NONH for all modes of transport
WGK德国 3
海关编码 2922399090
Name: 1-Amino-4-bromo-2-methylanthraquinone 95% Material Safety Data Sheet
Synonym:
CAS: 81-50-5
Section 1 - Chemical Product MSDS Name:1-Amino-4-bromo-2-methylanthraquinone 95% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
81-50-5 1-Amino-4-bromo-2-methylanthraquinone 95% 201-355-6
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 81-50-5: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Crystalline powder
Color: orange to red
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 245 - 252 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C15H10BrNO2
Molecular Weight: 316.15

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 81-50-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-Amino-4-bromo-2-methylanthraquinone - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 81-50-5: No information available.
Canada
CAS# 81-50-5 is listed on Canada's NDSL List.
CAS# 81-50-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 81-50-5 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

~90%

81-50-5结构式

81-50-5

文献:Dynapol Patent: US4196294 A1, 1980 ;

~%

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文献:US4051138 A1, ;

~14%

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文献:Journal of Organic Chemistry USSR (English Translation), , vol. 27, # 8 p. 1547 - 1549 Zhurnal Organicheskoi Khimii, , vol. 27, # 8 p. 1762 - 1764

~85%

81-50-5结构式

81-50-5

文献:Gornostaev, L. M.; Sakilidi, V. T. Journal of Organic Chemistry USSR (English Translation), 1980 , vol. 16, # 3 p. 562 - 565 Zhurnal Organicheskoi Khimii, 1980 , vol. 16, # 3 p. 642 - 645

~%

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81-50-5

文献:DE612958 , ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 20, p. 1304

~%

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81-50-5

文献:DE612958 , ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 20, p. 1304

~%

81-50-5结构式

81-50-5

文献:DE612958 , ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 20, p. 1304

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