乙酰丙酮酸乙酯 ,ethyl 2,4-dioxovalerate ,97%
产品编号:SIGMA-232564| CAS NO:615-79-2| 分子式:C7H10O4| 分子量:158.1519
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产品名称 | 乙酰丙酮酸乙酯 |
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英文名称 | ethyl 2,4-dioxovalerate |
CAS编号 | 615-79-2 |
产品熔点 | 16-18 °C(lit.) |
产品沸点 | 214.7±13.0 °C at 760 mmHg |
产品密度 | 1.1±0.1 g/cm3 |
产品闪点 | 85.8±19.9 °C |
精确质量 | 158.057907 |
PSA | 60.44000 |
LogP | -0.19 |
外观性状 | 透明非常淡黄色液体 |
蒸气压 | 0.2±0.4 mmHg at 25°C |
折射率 | 1.426 |
稳定性 | 性质与稳定性: 常温常压下,或不分解产物。 |
储存条件 | 贮存: 将密器密封,储存密封的主藏器内,并放在阴凉, 干爽的位置。 |
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个人防护装备 | Eyeshields;Gloves |
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危害码 (欧洲) | Xn |
风险声明 (欧洲) | R22 |
安全声明 (欧洲) | S23-S24/25 |
危险品运输编码 | NONH for all modes of transport |
WGK德国 | 3 |
海关编码 | 29183000 |
Synonym:None Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or appropriate foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 615-79-2: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: clear very slight yellow Odor: none reported pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 101 - 103 deg C @ 12.00mmHg Freezing/Melting Point: 16.00 - 18.00 deg C Autoignition Temperature: Not applicable. Flash Point: > 112 deg C (> 233.60 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Not available. Solubility in water: Not available. Specific Gravity/Density: 1.1260g/cm3 Molecular Formula: C7H10O4 Molecular Weight: 158.15 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, strong oxidants. Incompatibilities with Other Materials: Acids, bases, oxidizing agents, reducing agents. Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 615-79-2 unlisted. LD50/LC50: Not available. Carcinogenicity: Ethyl 2,4-dioxovalerate - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 615-79-2: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 615-79-2 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 615-79-2 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
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文献:Kraem, Jihene Ben; Amri, Hassen Synthetic Communications, 2013 , vol. 43, # 1 p. 110 - 117 |
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文献:Chemische Berichte, , vol. 20, p. 2188 |
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文献:Justus Liebigs Annalen der Chemie, , vol. 569, p. 17,27 |
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文献:Justus Liebigs Annalen der Chemie, , vol. 569, p. 17,27 |
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