烯丙基(二氯)甲基硅烷 ,allyldichloromethylsilane ,95%
产品编号:SIGMA-447277| CAS NO:1873-92-3| 分子式:C4H8Cl2Si| 分子量:155.0978
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产品名称 | 烯丙基(二氯)甲基硅烷 |
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英文名称 | allyldichloromethylsilane |
CAS编号 | 1873-92-3 |
产品沸点 | 119.8±9.0 °C at 760 mmHg |
产品密度 | 1.0±0.1 g/cm3 |
产品闪点 | 18.3±14.3 °C |
精确质量 | 153.977234 |
LogP | 4.01 |
外观性状 | 透明无色至淡黄色液体 |
蒸气压 | 18.8±0.2 mmHg at 25°C |
折射率 | 1.436 |
稳定性 | 常温常压下稳定,避免与不相容材料,火源,湿空气,水接触。 与潮湿的空气,水,酸,碱,醇,胺,氨,过氧化物,醛类(如乙醛,丙烯醛,三氯乙醛,甲醛),酮类(如丙酮,苯乙酮,丁酮,甲基异丁基酮)反应。 |
储存条件 | 密封储存,储存于阴凉、干燥的库房,避免与湿气,水源接触。干爽的惰性气体保护。 |
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符号 |
![]() ![]() GHS02, GHS05 |
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信号词 | Danger |
危害声明 | H225-H314 |
补充危害声明 | Reacts violently with water. |
警示性声明 | P210-P280-P305 + P351 + P338-P310 |
个人防护装备 | Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
危害码 (欧洲) | F: Flammable;C: Corrosive; |
风险声明 (欧洲) | R11 |
安全声明 (欧洲) | S16-S26-S36/37/39-S45 |
危险品运输编码 | UN 2985 3/PG 2 |
WGK德国 | 1 |
包装等级 | II |
危险类别 | 3 |
海关编码 | 2931900090 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 11 14 34 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Highly flammable. Reacts violently with water. Causes burns. Potential Health Effects Eye: Causes eye burns. Skin: Causes skin burns. Ingestion: Causes gastrointestinal tract burns. The toxicological properties of this substance have not been fully investigated. Inhalation: Causes chemical burns to the respiratory tract. The toxicological properties of this substance have not been fully investigated. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid immediately. Skin: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid immediately. Wash clothing before reuse. Ingestion: If swallowed, do NOT induce vomiting. Get medical aid immediately. If victim is fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Water Reactive. Material will react with water and may release a flammable and/or toxic gas. Containers may explode in the heat of a fire. Flammable liquid and vapor. Extinguishing Media: Use foam, dry chemical, or carbon dioxide. DO NOT USE WATER! Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. Do not expose spill to water. Section 7 - HANDLING and STORAGE Handling: Use spark-proof tools and explosion proof equipment. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood. Storage: Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Keep away from water. Flammables-area. Store under an inert atmosphere. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 1873-92-3: Personal Protective Equipment Eyes: Wear chemical splash goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: Clear Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 119-120 deg C Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: 20 deg C ( 68.00 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: reacts with water Specific Gravity/Density: 1.0670g/cm3 Molecular Formula: CH2CHCH2Si(CH3)Cl2 Molecular Weight: 155.10 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, ignition sources, exposure to moist air or water. Incompatibilities with Other Materials: Oxidizing agents, acids, bases, alcohols, amines, ammonia, peroxides, aldehydes (e.g. acetaldehyde, acrolein, chloral hydrate, formaldehyde), ketones (e.g. acetone, acetophenone, MEK, MIBK). Hazardous Decomposition Products: Hydrogen chloride, carbon monoxide, carbon dioxide, silicon dioxide. Hazardous Polymerization: Will not occur. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 1873-92-3 unlisted. LD50/LC50: Not available. Carcinogenicity: Allyldichloromethylsilane - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: Chlorosilanes, Flammable, Corrosive, N.O.S. Hazard Class: 3 UN Number: 2985 Packing Group: II IMO Shipping Name: Chlorosilanes, Flammable, Corrosive, N.O.S. Hazard Class: 3 UN Number: 2985 Packing Group: II RID/ADR Shipping Name: Chlorosilanes, Flammable, Corrosive, N.O.S. Hazard Class: 3 UN Number: 2985 Packing group: Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: F C Risk Phrases: R 11 Highly flammable. R 14 Reacts violently with water. R 34 Causes burns. Safety Phrases: S 8 Keep container dry. S 16 Keep away from sources of ignition - No smoking. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 1873-92-3: No information available. Canada CAS# 1873-92-3 is listed on Canada's NDSL List. CAS# 1873-92-3 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 1873-92-3 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A |