二乙基二硫代磷酸铵盐 ,Diethyl dithiophosphate, ammonium salt ,95%

产品编号:SIGMA-177792| CAS NO:1068-22-0| 分子式:C4H12NO2PS2| 分子量:201.2473

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SIGMA-177792
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产品名称 二乙基二硫代磷酸铵盐
英文名称Diethyl dithiophosphate, ammonium salt
CAS编号1068-22-0
产品熔点164-166 °C(lit.)
产品沸点232.7ºC at 760mmHg
产品密度1.214g/cm3
产品闪点94.5ºC
精确质量203.02000
PSA102.40000
LogP3.18820
蒸气压0.0153mmHg at 25°C
折射率1.546
稳定性

常温常压下稳定,避免氧化物接触

储存条件

保持容器密封,储存在阴凉,干燥的地方

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符号 GHS07
GHS07
信号词 Warning
危害声明 H302 + H312 + H332
警示性声明 P280
个人防护装备 dust mask type N95 (US);Eyeshields;Gloves
危害码 (欧洲) Xn
风险声明 (欧洲) 20/21/22
安全声明 (欧洲) S36
危险品运输编码 UN 3335
WGK德国 3
RTECS号 BP8145000
海关编码 2931900090
Name: Diethyl Dithiophosphate Ammonium Salt 95% Material Safety Data Sheet
Synonym: Ammonium O,O-Diethyl Diethiophosphate; Phosphorodithioic Acid, O,O-Diethyl Ester, Ammonium Salt
CAS: 1068-22-0
Section 1 - Chemical Product MSDS Name:Diethyl Dithiophosphate Ammonium Salt 95% Material Safety Data Sheet
Synonym:Ammonium O,O-Diethyl Diethiophosphate; Phosphorodithioic Acid, O,O-Diethyl Ester, Ammonium Salt

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
1068-22-0 Diethyl Dithiophosphate, Ammonium Salt 95 213-942-4
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. Low hazard for usual industrial handling.
Inhalation:
May cause respiratory tract irritation. Low hazard for usual industrial handling.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. If irritation develops, get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water. Get medical aid if irritation or symptoms occur.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. No special precautions indicated.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 1068-22-0: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Crystals
Color: white
Odor: ammonia-like - unpleasant odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 164.00 - 166.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C4H14NO2PS2
Molecular Weight: 203.25

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, sulfur oxides (SOx), including sulfur oxide and sulfur dioxide, phosphorous fumes, ammonia.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 1068-22-0: BP8145000 LD50/LC50:
CAS# 1068-22-0: Draize test, rabbit, skin: 500 mg Mild; Oral, rat: LD50 = 7900 mg/kg.
Carcinogenicity:
Diethyl Dithiophosphate, Ammonium Salt - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1068-22-0: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 1068-22-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1068-22-0 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

~%

1068-22-0结构式

1068-22-0

文献:WO2005/95425 A1, ; Page/Page column 26-27 ;

~97%

1068-22-0结构式

1068-22-0

文献:Kaboudin, Babak; Norouzi, Hamid Synthesis, 2004 , # 12 p. 2035 - 2039

~%

1068-22-0结构式

1068-22-0

文献:J. Gen. Chem. USSR (Engl. Transl.), , vol. 51, # 4 p. 738 - 745,602 - 608

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