2-氯苯基硫脲,2-Chlorophenylthiourea,98%
产品编号:Bellancom-C44101| CAS NO:5344-82-1| MDL NO:MFCD00004934| 分子式:C7H7ClN2S| 分子量:Null,without related properties.
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产品名称 | 2-氯苯基硫脲 |
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英文名称 | 2-Chlorophenylthiourea,98% |
CAS编号 | 5344-82-1 |
产品熔点 | 144-149 °C |
产品沸点 | 293.1ºC at 760mmHg |
产品密度 | 1.441g/cm3 |
产品闪点 | 131.1ºC |
精确质量 | 186.00200 |
PSA | 70.14000 |
LogP | 2.76880 |
外观性状 | 针状或板 |
折射率 | 1.727 |
稳定性 | 常温常压下稳定,本品为白色或淡黄色固体,m.p.143~146℃,易溶于乙醇,易溶于水。 |
储存条件 | 避光,阴凉干燥处,密封保存 |
相关文档
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危害码 (欧洲) | T+:Verytoxic; |
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风险声明 (欧洲) | R28 |
安全声明 (欧洲) | S45-S28A-S1 |
危险品运输编码 | 2811 |
RTECS号 | YS7100000 |
包装等级 | II |
危险类别 | 6.1 |
海关编码 | 2930909090 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 28 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Very toxic if swallowed. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. May be harmful if absorbed through the skin. Ingestion: May be fatal if swallowed. May cause irritation of the digestive tract. Inhalation: May cause respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid immediately. Wash mouth out with water. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood. Storage: Store in a cool, dry place. Store in a tightly closed container. Poison room locked. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 5344-82-1: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Powder Color: white to tan Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 143 - 146 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C7H7ClN2S Molecular Weight: 186.66 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents, strong acids, strong bases. Hazardous Decomposition Products: Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide, sulfur oxides (SOx), including sulfur oxide and sulfur dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 5344-82-1: YS7100000 LD50/LC50: CAS# 5344-82-1: Oral, rat: LD50 = 4600 ug/kg. Carcinogenicity: 1-(2-Chlorophenyl)-2-thiourea - Not listed by ACGIH, IARC, or NTP. Other: See actual entry in RTECS for complete information. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.* Hazard Class: 6.1 UN Number: 2811 Packing Group: II IMO Shipping Name: TOXIC SOLID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2811 Packing Group: II RID/ADR Shipping Name: TOXIC SOLID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2811 Packing group: II USA RQ: CAS# 5344-82-1: 100 lb final RQ; 45.4 kg final RQ Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: T+ Risk Phrases: R 28 Very toxic if swallowed. Safety Phrases: S 1 Keep locked up. S 28A After contact with skin, wash immediately with plenty of water. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 5344-82-1: No information available. Canada CAS# 5344-82-1 is listed on Canada's NDSL List. CAS# 5344-82-1 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 5344-82-1 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A |
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文献:THE BOARD OF TRUSTEES OF THE LELAND STANFORD JUNIOR UNIVERSITY; AUCKLAND UNISERVICES LIMITED Patent: WO2009/114552 A1, 2009 ; Location in patent: Page/Page column 141 ; |
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文献:Kodomari, Mitsuo; Suzuki, Masato; Tanigawa, Keiko; Aoyama, Tadashi Tetrahedron Letters, 2005 , vol. 46, # 35 p. 5841 - 5843 |
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文献:Journal of the Chemical Society, , p. 3043 |
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文献:Bioorganic and Medicinal Chemistry Letters, , vol. 15, # 23 p. 5211 - 5217 |
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文献:Tetrahedron Letters, , vol. 50, # 20 p. 2407 - 2410 |
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文献:Uberhande; Thakare; Berad Journal of the Indian Chemical Society, 2010 , vol. 87, # 9 p. 1137 - 1141 |
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文献:Bioorganic and Medicinal Chemistry Letters, , vol. 11, # 7 p. 915 - 918 |
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文献:Bioorganic and Medicinal Chemistry Letters, , vol. 20, # 3 p. 1177 - 1180 |
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