铥/介质:5%硝酸,标准溶液,溶剂:水, 1000mg/L

产品编号:西域质检-TM20207| CAS NO:15631-58-0| 分子式:C33H60O6Tm| 分子量:721.76000

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货号 包装 价格 库存与货期 购买量 操作
西域质检-TM20207
240.00 杭州 北京(现货)

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铥/介质:5%硝酸

本标准物质主要用于测量仪器校准,分析方法确认与评价,测量过程质量控制,也可用于量值溯源或作为标准储备溶液,通过逐级稀释配制成各种工作用标准溶液。 本标准物质适用于电感耦合等离子体发射光谱法(ICP-OES),电感耦合等离子体质谱法(ICP-MS),原子吸收光谱法(AAS)等方法分析测试使用。

一、样品制备

本标准物质以纯度经准确定值的高纯金属铥,优级纯硝酸和符合国家一级水标准的纯水为原料,在(20±3)℃的条件下采用重量-容量法准确配制而成。

二、溯源性及定值方法

本标准物质以配制值作为标准值,采用电感耦合等离子体发射光谱法(ICP-OES)进行量值核验。通过使用满足计量学特性要求的制备方法,测量方法和计量器具,保证标准物质的量值溯源性。

三、特性量值及不确定度

标准值:1000mg/L,相对扩展不确定度(k=2):1%,基体(V/V):5%硝酸
 标准值的不确定度综合考虑了原料纯度定值结果,制备过程,量值核验以及均匀性,稳定性等引入的不确定度分量。

四、均匀性检验及稳定性考察

依据JJF1343-2022《标准物质的定值及均匀性、稳定性评估》,对分装后的样品进行随机抽样,对溶液浓度进行均匀性检验,稳定性考察。结果表明,本标准物质均匀性,稳定性良好。
 本标准物质量值自定值日期起,有效期24个月,研制单位将继续跟踪监测该标准物质的稳定性,有效期内如发现量值变化,将及时通知用户。

五、包装、运输和贮存、使用及注意事项

1、包装: 本标准物质采用高密度聚乙烯(HDPE)瓶包装,50mL/瓶,移取或稀释时请以移液管量取为准。
 2、贮存:运输时应避免挤压,碰撞;常温(20±5)℃,置于阴凉处贮存。
 3、使用: 使用前应恒温至(20±3)℃,并充分摇匀。本标准物质打开后应尽快使用,避免玷污。

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WGK德国 3

Section 1: Product Identification
Chemical Name:Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)thulium (III), 98% (99.9%-Tm) (REO) Tm(TMHD)3
CAS Registry Number:15631-58-0
Formula:Tm(C11H19O2)3
EINECS Number:none
Chemical Family:metal beta-diketonate complexes
Synonym:Thulium (III) TMHD, Thulium (III) THD

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound15631-58-0100%no datano data

Section 3: Hazards Identification
Emergency Overview:No particular hazard associated with this material.
Primary Routes of Exposure:Ingestion
Eye Contact:May cause slight to mild irritation of the eyes.
Skin Contact:May cause slight to mild irritation of the skin.
Inhalation:May be irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No information on the effects of ingestion.
Acute Health Affects:May be irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:none
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, foam or dry powder
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self- contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit irritating fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store in a tightly sealed container.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothes and gloves. Consult glove manufacturer to determine the proper type of glove.
Ventilation:If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:off-white xtl.
Molecular Weight:718.75
Melting Point:169-172°C
Boiling Point:280°C (decomposes)
Vapor Pressure:no data
Specific Gravity:no data
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture-stable solid
Hazardous Polymerization:none
Conditions to Avoid:none
Incompatibility:strong oxidizing agents
Decomposition Products:carbon dioxide, carbon monoxide, organic fumes and thulium oxide.

SECTION 11: Toxicological Information
RTECS Data:No information available from RTECS.
Carcinogenic Effects:No data available
Mutagenic Effects:No data available
Tetratogenic Effects:No data available

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed on the TSCA inventory.
SARA (Title 313):Not reportable under SARA 313.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

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