4-氟苯氧乙酸,标准溶液,溶剂:乙腈, 100μg/mL
产品编号:西域质检-TM21487| CAS NO:405-79-8| 分子式:C8H7FO3| 分子量:170.138
4-Fluorophenoxyacetic acid (4FPA) 可诱导单性结实。4-Fluorophenoxyacetic acid (4FPA) 可保护谷物免受吸虫的侵害从而提高田间水稻产量。
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4-氟苯氧乙酸
This certificate is designed in accordance with ISO 17034 and ISO Guide 31. This reference material (RM) was designed,produced and verified in accordance with ISO/IEC 17025, ISO 17034 and a registered quality management system ISO 9001.
冷冻(-18±5)℃,置于阴凉处

QC Test Results | ||||
Item | Test Results | |||
Analysis method(分析方法) | HPLC/DAD | |||
Concentration(浓度) | 100μg/mL | |||
Relative Expanded Uncertainty(k=2)(相对扩展不确定度) | 3% | |||
Expiry Date(失效日期) | 2023-Dec-12 |
The certified value(s) and uncertainty(ies) are determined in accordance with ISO 17034 with an 95% confidence level (k=2). Uncertainty is based on the Total Combined Uncertainty, including uncertainties of preparation, purity of neat materials, homogeneity, stability testing.
The balances used for gravimetric measurements are calibrated with weights traceable to the national standards. The calibration of the balances is verified annually by an external accredited calibration service. This analysis method has been verified using an approach consistent with ISO 17034:2016 & ISO 17025:2017.
CERTIFICATE ON | QC SIGNATURE | |
2022-Dec-13 |
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个人防护装备 | Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter |
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危害码 (欧洲) | Xn:Harmful; |
风险声明 (欧洲) | R22;R36/37/38 |
安全声明 (欧洲) | S37/39-S26 |
危险品运输编码 | NONH for all modes of transport |
WGK德国 | 3 |
海关编码 | 2918990090 |
Synonym:None Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or appropriate foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 405-79-8: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Powder Color: white Odor: none reported pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 104.00 - 104.50 deg C Autoignition Temperature: Not applicable. Flash Point: Not applicable. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Not available. Solubility in water: Not available. Specific Gravity/Density: Not available. Molecular Formula: C8H7FO3 Molecular Weight: 170.14 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, strong oxidants. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen fluoride gas. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 405-79-8 unlisted. LD50/LC50: Not available. Carcinogenicity: 4-Fluorophenoxyacetic acid - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 405-79-8: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 405-79-8 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 405-79-8 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
~% ![]() 405-79-8 |
文献:Chevron Research Company Patent: US4620867 A1, 1986 ; |
~63% ![]() 405-79-8 |
文献:Heescher, Carolin; Schollmeyer, Dieter; Nubbemeyer, Udo European Journal of Organic Chemistry, 2013 , # 20 p. 4399 - 4404 |
~% ![]() 405-79-8 |
文献:Xia, Yan; Won, Misun; Kang, Jung Eun; Park, Song-Kyu; Lee, Kiho; Kim, Hwan-Mook; Lee, Kyeong Bulletin of the Korean Chemical Society, 2010 , vol. 31, # 12 p. 3826 - 3829 |
~69% ![]() 405-79-8 |
文献:Chen, Ting; Shen, Ping; Li, Yanjun; He, Hongwu Phosphorus, Sulfur and Silicon and the Related Elements, 2006 , vol. 181, # 9 p. 2135 - 2145 |
~% ![]() 405-79-8 |
文献:Suter; Lawson; Smith Journal of the American Chemical Society, 1939 , vol. 61, p. 161,164 |
~% ![]() 405-79-8 |
文献:Suter; Lawson; Smith Journal of the American Chemical Society, 1939 , vol. 61, p. 161,164 |
~% ![]() 405-79-8 |
文献:Gurumurthy, R.; Balakrishnan, N. Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1982 , vol. 21, # 2 p. 154 - 156 |
~% ![]() 405-79-8 |
文献:Molenaar-Langeveld, Tineke A.; Ingemann, Steen; Nibbering, Nico M. M. Organic Mass Spectrometry, 1993 , vol. 28, # 10 p. 1167 - 1178 |
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