乐杀螨,标准溶液,溶剂:乙腈, 1000μg/mL
产品编号:西域质检-TM21410| CAS NO:485-31-4| 分子式:C15H18N2O6| 分子量:322.313
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乐杀螨
本标准物质主要用于测量仪器校准,分析方法评价和质量控制,以及食品,卫生,环境和农业等领域相应成分含量测定与残留检测,也可用于量值溯源或作为标准储备溶液,通过逐级稀释配制成各种工作用标准溶液等。
本标准物质以纯度经准确定值的乐杀螨纯品为原料 , 以HPLC级乙腈为溶剂 , 采用重量-容量法准确配制而成 。
乐杀螨,英文名称: Binapacryl,CAS No. :485-31-4
本标准物质以配制值作为标准值,采用高效液相色谱法-二极管阵列检测器(HPLC-DAD)对本批次标准物质和质量控制对照样品进行比对,核验配制值。通过使用满足计量学特性要求的制备方法,测量方法和计量器具,保证标准物质的量值溯源性。
标准值:1000μg/mL,相对扩展不确定度(k=2):2%
标准值的不确定度综合考虑了原料纯度定值结果,制备过程,量值核验以及均匀性,稳定性等引入的不确定度分量。
依据JJF1343-2022《标准物质的定值及均匀性、稳定性评估》 ,对分装后的样品进行随机抽样。采用钼酸铵分光光度法对溶液浓度进行均匀性检验,稳定性考察。结果表明,本标准物质均匀性,稳定性良好。
本标准物质量值自定值日期起,有效期18个月, 研制单位将继续跟踪监测该标准物质的稳定性,有效期内如发现量值变化,将及时通知用户。
1、包装: 本标准物质采用硼硅酸盐玻璃安瓿瓶包装,约1.2mL/支,移取或稀释时请以移液管量取为准。
2、贮存:运输时应避免挤压,碰撞;冷冻(-18±5)℃,置于阴凉处贮存。
3、使用: 启封前于室温(20±3)℃平衡,并充分摇匀。安瓿瓶一经打开,应立即使用,不可再次熔封后作为标准物质使用。
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符号 |
![]() ![]() ![]() GHS07, GHS08, GHS09 |
---|---|
信号词 | Danger |
危害声明 | H302 + H312-H360D-H410 |
警示性声明 | P201-P273-P280-P308 + P313-P501 |
个人防护装备 | dust mask type N95 (US);Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges |
危害码 (欧洲) | T: Toxic;N: Dangerous for the environment; |
风险声明 (欧洲) | 61-21/22-50/53 |
安全声明 (欧洲) | 53-45-60-61 |
危险品运输编码 | 2779 |
WGK德国 | 3 |
RTECS号 | GQ5600000 |
包装等级 | III |
危险类别 | 6.1(b) |
Section1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE Product identifiers Product name: Binapacryl Index-No.: 609-024-00-1 CAS-No.: 485-31-4 Relevant identified uses of the substance or mixture and uses advised against Identified uses: Laboratory chemicals, Manufacture of substances
Section2. HAZARDS IDENTIFICATION Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP] Reproductive toxicity (Category 1B) Acute toxicity (Category 4) Acute toxicity (Category 4) Acute aquatic toxicity (Category 1) Chronic aquatic toxicity (Category 1) Classification according to EU Directives 67/548/EEC or 1999/45/EC May cause harm to the unborn child. Harmful in contact with skin and if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Label elements Labelling according Regulation (EC) No 1272/2008 [CLP] Pictogram Signal wordDanger Hazard statement(s) H302Harmful if swallowed. H312Harmful in contact with skin. H410Very toxic to aquatic life with long lasting effects. H360DMay damage the unborn child. Precautionary statement(s) P201Obtain special instructions before use. P273Avoid release to the environment. P280Wear protective gloves/ protective clothing. P308 + P313IF exposed or concerned: Get medical advice/ attention. P501Dispose of contents/ container to an approved waste disposal plant. Supplemental Hazardnone Statements According to European Directive 67/548/EEC as amended. Hazard symbol(s) R-phrase(s) R61May cause harm to the unborn child. R21/22Also harmful in contact with skin and if swallowed. R50/53Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s) S53Avoid exposure - obtain special instructions before use. S45In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S60This material and its container must be disposed of as hazardous waste. S61Avoid release to the environment. Refer to special instructions/ Safety data sheets. Restricted to professional users. Other hazards - none Section3. COMPOSITION/INFORMATION ON INGREDIENTS Substances Formula: C15H18N2O6 Molecular Weight: 322,31 g/mol ComponentConcentration Binapacryl CAS-No.485-31-4- EC-No.207-612-9 Index-No.609-024-00-1 Section4. FIRST AID MEASURES Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician. In case of eye contact Flush eyes with water as a precaution. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Most important symptoms and effects, both acute and delayed Indication of any immediate medical attention and special treatment needed no data available Section5. FIREFIGHTING MEASURES Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special hazards arising from the substance or mixture Carbon oxides, nitrogen oxides (NOx) Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Further information no data available Section6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Wear respiratory protection. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Methods and materials for containment and cleaning up Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. Reference to other sections For disposal see section 13. Section7. HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes. Avoid formation of dust and aerosols.Avoid exposure - obtain special instructions before use. Provide appropriate exhaust ventilation at places where dust is formed. Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Specific end use(s) no data available Section8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Section9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties a) AppearanceForm: solid b) Odourno data available c) Odour Thresholdno data available d) pHno data available e) Melting point/freezingno data available point f) Initial boiling point and no data available boiling range g) Flash pointno data available h) Evaporation rateno data available i) Flammability (solid, gas) no data available j) Upper/lowerno data available flammability or explosive limits k) Vapour pressureno data available l) Vapour densityno data available m) Relative densityno data available n) Water solubilityno data available o) Partition coefficient: n- no data available octanol/water p) Auto-ignitionno data available temperature q) Decompositionno data available temperature r) Viscosityno data available s) Explosive propertiesno data available t) Oxidizing propertiesno data available Other safety information no data available Section10. STABILITY AND REACTIVITY Reactivity no data available Chemical stability no data available Possibility of hazardous reactions no data available Conditions to avoid no data available Incompatible materials Strong oxidizing agents Hazardous decomposition products Other decomposition products - no data available Section11. TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity LD50 Oral - rat - 58 mg/kg LD50 Dermal - rabbit - 750 mg/kg Skin corrosion/irritation no data available Serious eye damage/eye irritation no data available Respiratory or skin sensitization no data available Germ cell mutagenicity no data available Carcinogenicity IARC:No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity May cause congenital malformation in the fetus. Presumed human reproductive toxicant Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Potential health effects InhalationMay be harmful if inhaled. May cause respiratory tract irritation. IngestionToxic if swallowed. Skin Toxic if absorbed through skin. May cause skin irritation. EyesMay cause eye irritation. Additional Information RTECS: GQ5600000 Section12. ECOLOGICAL INFORMATION Toxicity Toxicity to fishmortality LOEC - Salmo salar (Atlantic salmon) - 0,06 mg/l - 96,0 h LC50 - Oncorhynchus mykiss (rainbow trout) - 0,05 mg/l - 96,0 h Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available Results of PBT and vPvB assessment no data available Other adverse effects Very toxic to aquatic life. Section13. DISPOSAL CONSIDERATIONS Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Contaminated packaging Dispose of as unused product. Section14. TRANSPORT INFORMATION UN number ADR/RID: 2811IMDG: 2811IATA: 2811 UN proper shipping name ADR/RID: TOXIC SOLID, ORGANIC, N.O.S. (Binapacryl) IMDG: TOXIC SOLID, ORGANIC, N.O.S. (Binapacryl) IATA:Toxic solid, organic, n.o.s. (Binapacryl) Transport hazard class(es) ADR/RID: 6.1IMDG: 6.1IATA: 6.1 Packaging group ADR/RID: IIIIMDG: IIIIATA: III Environmental hazards ADR/RID: yesIMDG Marine Pollutant: yesIATA: no Special precautions for user no data available Section15. REGULATORY INFORMATION This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. Safety, health and environmental regulations/legislation specific for the substance or mixture no data available Chemical Safety Assessment no data available Section16. OTHER INFORMATION Further information Copyright 2012 Co. LLC. License granted to make unlimited paper copies for internal use only. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Corporation and its Affiliates shall not be held liable for any damage resulting from handling or from contact with the above product. See and/or the reverse side of invoice or packing slip for additional terms and conditions of sale. |