8-羟基喹啉铜,8-Hydroxyquinoline copper complex,标准溶液,100μg/ml,溶剂:甲醇

产品编号:西域质检-TM21355| CAS NO:10380-28-6| 分子式:C18H12CuN2O2| 分子量:351.846

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货号 包装 价格 库存与货期 购买量 操作
西域质检-TM21355
350.00 杭州 北京(现货)

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8-羟基喹啉铜

本标准物质主要用于测量仪器校准,分析方法评价和质量控制,以及食品,卫生,环境和农业等领域相应成分含量测定与残留检测,也可用于量值溯源或作为标准储备溶液,通过逐级稀释配制成各种工作用标准溶液等。


一、样品制备

本标准物质以纯度经准确定值的喹啉铜纯品为原料,以HPLC级甲醇为溶剂,采用重量-容量法准确配制而成。
喹啉铜,英文名称: Oxine-Copper,CAS No. : 10380-28-6


二、溯源性及定值方法

本标准物质以配制值作为标准值,采用⾼效液相⾊谱法-⼆极管阵列检测器(HPLC-DAD)对本批次标准物质和质量控制对照样品进行比对,核验配制值。通过使用满足计量学特性要求的制备方法,测量方法和计量器具,保证标准物质的量值溯源性。


三、特性量值及不确定度

标准值:100μg/mL,相对扩展不确定度(k=2):3%
标准值的不确定度综合考虑了原料纯度定值结果,制备过程,量值核验以及均匀性,稳定性等引入的不确定度分量。


四、均匀性检验及稳定性考察

依据JJF1343-2022《标准物质的定值及均匀性、稳定性评估》,对分装后的样品进行随机抽样,对溶液浓度进行均匀性检验,稳定性考察。结果表明,本标准物质均匀性,稳定性良好。
本标准物质量值自定值日期起,有效期12个月, 研制单位将继续跟踪监测该标准物质的稳定性,有效期内如发现量值变化,将及时通知用户。


五、包装、运输和贮存、使用及注意事项

1、包装: 本标准物质采用硼硅酸盐玻璃安瓿瓶包装,约1.2mL/支,移取或稀释时请以移液管量取为准。
2、贮存: 运输时应避免挤压,碰撞;冷冻(-18±5)℃,置于阴凉处贮存。
3、使用: 启封前于室温(20±3)℃平衡,并充分摇匀。安瓿瓶一经打开,应立即使用,不可再次熔封后作为标准物质使用。

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危害码 (欧洲) Xi
风险声明 (欧洲) R36/37/38
安全声明 (欧洲) S26-S36
危险品运输编码 UN 3077 9/PG 3
WGK德国 3
RTECS号 VC5250000
海关编码 2933499090

Section 1. Chemical Product and Company Identification
8-Hydroxyquinoline, Copper Salt
Common Name/
Trade Name
Manufacturer
Commercial Name(s)
Synonym
Chemical Name
Chemical Family
8-Hydroxyquinoline, Copper Salt

Section 4. First Aid Measures
Eye ContactCheck for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at
least 15 minutes. Get medical attention.
Skin ContactIn case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove
contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get
medical attention.
Serious Skin ContactWash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical
attention.
InhalationIf inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
medical attention.
Serious InhalationNot available.
IngestionDo NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if
symptoms appear.
Serious IngestionNot available.

Section 5. Fire and Explosion Data
Flammability of the Product May be combustible at high temperature.
Auto-Ignition Temperature Not available.
Flash PointsNot available.
Flammable LimitsNot available.
Products of CombustionThese products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...).
Fire Hazards in Presence of Slightly flammable to flammable in presence of heat.
Various Substances
Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
of Various SubstancesRisks of explosion of the product in presence of static discharge: Not available.
Fire Fighting MediaSMALL FIRE: Use DRY chemical powder.
and InstructionsLARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Special Remarks onNot available.
Fire Hazards
Special Remarks on Explosion Not available.
Hazards

Section 6. Accidental Release Measures
Small SpillUse appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by
spreading water on the contaminated surface and dispose of according to local and regional authority
requirements.
Large SpillUse a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water
on the contaminated surface and allow to evacuate through the sanitary system.
8-Hydroxyquinoline, Copper Salt

Section 7. Handling and Storage
PrecautionsKeep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not
ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable
respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid
contact with skin and eyes.
StorageKeep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 8°C (46.4°F).
Refrigerate.

Section 8. Exposure Controls/Personal Protection
Engineering ControlsUse process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to
airborne contaminants below the exposure limit.
Personal ProtectionSplash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used
a Large Spillto avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist
BEFORE handling this product.
Exposure LimitsNot available.

Section 9. Physical and Chemical Properties
Physical state and appearance Solid. (crystalline powder)OdorNot available.
Not available.
Taste
Molecular Weight351.85 g/mole
greenish-yellow
Color
Not applicable.
pH (1% soln/water)
Boiling PointNot available.
Melting Point>200°C (392°F)
Critical TemperatureNot available.
Specific GravityNot available.
Not applicable.
Vapor Pressure
Vapor DensityNot available.
Not available.
Volatility
Odor ThresholdNot available.
Water/Oil Dist. Coeff.Not available.
Ionicity (in Water)Not available.
Dispersion PropertiesNot available.
SolubilityInsoluble in cold water, hot water.

Section 10. Stability and Reactivity Data
StabilityThe product is stable.
Instability TemperatureNot available.
Conditions of InstabilityExcess heat, excess dust generation
Incompatibility with variousNot available.
substances
CorrosivityNot available.
8-Hydroxyquinoline, Copper Salt
Special Remarks onNot available.
Reactivity
Special Remarks onNot available.
Corrosivity
PolymerizationWill not occur.

Section 11. Toxicological Information
Routes of EntryInhalation. Ingestion.
Toxicity to AnimalsAcute oral toxicity (LD50): 3940 mg/kg [Mouse].
Acute dermal toxicity (LD50): >2000 mg/kg [Rabbit].
Chronic Effects on Humans MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast.
Other Toxic Effects onHazardous in case of inhalation.
HumansSlightly hazardous in case of skin contact (irritant, permeator), of ingestion.
Special Remarks onLethal Dose/Conc 50% Kill:
Toxicity to AnimalsLC50 [Rat] - Route: Inhalation; Dose: 820 mg/kg.
*Please Note that the time period for testing was not indicated by the Registery of Toxic Effects of Chemial
Substances (RTECS).
Special Remarks onMay affect genetic material and may cause cancer based on animal data. No human data found.
Chronic Effects on Humans
Special Remarks on otherAcute Potential Health Effects:
Toxic Effects on HumansSkin: May cause skin irritation. It may be absorbed through the skin.
Eye: Dust may cause eye irritation.
Inhalation: Dust may cause respiratory tract irritation. May be harmful if inhaled.
Ingestion: May affect behavior (somnolence - general depressed activity), gastrointestinal tract (irritation,
diarrhea, hypermotility), repiratory system (dyspnea), nervous system
Chronic Potential Health Effects: liver (hepatitis), urinary system, spleen, metabolism (weight loss), blood.

Section 12. Ecological Information
EcotoxicityNot available.
BOD5 and CODNot available.
Possibly hazardous short term degradation products are not likely. However, long term degradation products may
Products of Biodegradation
arise.
The products of degradation are less toxic than the product itself.
Toxicity of the Products
of Biodegradation
Special Remarks on theNot available.
Products of Biodegradation

Section 13. Disposal Considerations
Waste DisposalWaste must be disposed of in accordance with federal, state and local environmental
control regulations.
8-Hydroxyquinoline, Copper Salt

Section 14. Transport Information
DOT ClassificationNot a DOT controlled material (United States).
IdentificationNot applicable.
Not applicable.
Special Provisions for
Transport
DOT (Pictograms)

Section 15. Other Regulatory Information and Pictograms
TSCA 8(b) inventory: 8-Hydroxyquinoline, Copper Salt
Federal and State
Regulations
CaliforniaCalifornia prop. 65: This product contains the following ingredients for which the State of California has found
to cause cancer which would require a warning under the statute: No products were found.
Proposition 65
Warnings
California prop. 65: This product contains the following ingredients for which the State of California has found
to cause birth defects which would require a warning under the statute: No products were found.
Other RegulationsEINECS: This product is on the European Inventory of Existing Commercial Chemical Substances (EINECS No.
233-841-9).
Canada: Listed on Canadian Non-Domestic Substance List (NDSL).
China: Listed on National Inventory.
Japan: Listed on National Inventory (ENCS).
Korea: Listed on National Inventory (KECI).
Philippines: Listed on National Inventory (PICCS).
Australia: Listed on AICS.
WHMIS (Canada) CLASS D-1B: Material causing immediate and serious toxic effects (TOXIC).
Other Classifications
DSCL (EEC)
R20- Harmful by inhalation.S22- Do not breathe dust.
Health Hazard
HMIS (U.S.A.)2 National Fire Protection
1 Flammability
1 Association (U.S.A.)
Fire Hazard
2 0 Reactivity
Health
Reactivity
0
Specific hazard
Personal Protection
E
WHMIS (Canada)
(Pictograms)
DSCL (Europe)
(Pictograms)
TDG (Canada)
(Pictograms)
8-Hydroxyquinoline, Copper Salt
ADR (Europe)
(Pictograms)
Protective Equipment
Gloves.
Lab coat.
Dust respirator. Be sure to use an
approved/certified respirator or
equivalent.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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