环丁基甲酸甲酯, ≥99%,Methyl Cyclobutanecarboxylate

产品编号:西域试剂-WR338085| CAS NO:765-85-5| MDL NO:MFCD00095142| 分子式:C6H10O2| 分子量:114.14

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货号 包装 价格 库存与货期 购买量 操作
西域试剂-WR338085
98.00 杭州 北京(现货)
西域试剂-WR338085
347.00 杭州 北京(现货)
西域试剂-WR338085
1652.00 杭州 北京(现货)

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英文名称Methyl Cyclobutanecarboxylate
CAS编号765-85-5
产品沸点138.7±8.0 °C at 760 mmHg
产品密度1.1±0.1 g/cm3
产品闪点30.1±6.0 °C
精确质量114.068077
PSA26.30000
LogP1.11
外观性状透明无色液体
蒸气压6.6±0.3 mmHg at 25°C
折射率1.454
储存条件

密封储存,储存于阴凉、干燥的库房。

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安全声明 (欧洲) S24/25
危险品运输编码 UN 3272 3/PG III
包装等级 III
海关编码 2916209090
Name: Methyl cyclobutanecarboxylate 98% Material Safety Data Sheet
Synonym: None Known
CAS: 765-85-5
Section 1 - Chemical Product MSDS Name:Methyl cyclobutanecarboxylate 98% Material Safety Data Sheet
Synonym:None Known

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
765-85-5 Methyl cyclobutanecarboxylate 98% unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. May be harmful if inhaled.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove contaminated clothing and shoes. Get medical aid if irritation develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 765-85-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Clear liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C6H10O2
Molecular Weight: 114.14

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not currently available.
Conditions to Avoid:
Excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 765-85-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Methyl cyclobutanecarboxylate - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 765-85-5: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 765-85-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 765-85-5 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

~74%

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文献:Shiner, V. J.; Tai, Jimmy J. Journal of the American Chemical Society, 1981 , vol. 103, # 2 p. 436 - 442

~93%

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文献:Madder, Annemieke; Sebastian, Sonny; Van Haver, Dirk; De Clercq, Pierre J.; Maskill, Howard Journal of the Chemical Society. Perkin Transactions 2, 1997 , # 12 p. 2787 - 2793

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文献:Collection of Czechoslovak Chemical Communications, , vol. 44, p. 2426 - 2437

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文献:European Journal of Organic Chemistry, , # 4 p. 579 - 584

~52%

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文献:Journal of Chemical Research, Miniprint, , # 1 p. 183 - 197

~30%

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文献:Giomini, Claudio; Inesi, Achille; Zeuli, Errico Journal of Chemical Research, Miniprint, 1983 , # 11 p. 2401 - 2416

~%

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765-85-5

文献:Journal of the Chemical Society, , p. 1804,1806

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