二氯(N,N,N′,N′-四甲基乙二胺)钯, 99%,Pd>36.2%,Dichloro(N,N,N′,N′-tetramethylethylenediamine)palladium(II)

产品编号:西域试剂-WR342494| CAS NO:14267-08-4| MDL NO:MFCD00075317| 分子式:[(CH3)2NCH2CH2N(CH3)2]PdCl2| 分子量:293.53

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西域试剂-WR342494
141.00 杭州 北京(现货)
西域试剂-WR342494
416.00 杭州 北京(现货)
西域试剂-WR342494
1196.00 杭州 北京(现货)

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英文名称Dichloro(N,N,N′,N′-tetramethylethylenediamine)palladium(II)
CAS编号14267-08-4
产品熔点245ºC (dec.)(lit.)
产品沸点121ºC at 760 mmHg
产品闪点10ºC
精确质量291.972534
PSA6.48000
LogP1.48860
蒸气压14.9mmHg at 25°C
稳定性

遵照规定使用和储存则不会分解。

储存条件

密闭于阴凉干燥环境中

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符号 GHS07
GHS07
信号词 Warning
危害声明 H315-H319-H335
警示性声明 P261-P305 + P351 + P338
个人防护装备 dust mask type N95 (US);Eyeshields;Gloves
危害码 (欧洲) Xi: Irritant;
风险声明 (欧洲) R36/37/38
安全声明 (欧洲) 37/39-26
危险品运输编码 NONH for all modes of transport

Section 1: Product Identification
Chemical Name:cis-Dichloro(N,N,N'N'-tetramethylethylenediamine)palladium(II), 99%
CAS Registry Number:14267-08-4
Formula:C6H16Cl2N2Pd
EINECS Number:none
Chemical Family:organometallic complex
Synonym:cis-ichloroN,N,N',N'-Tetramethyl-ethane-1,2-diamine)palladium(II)

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound14267-08-4100%no datano data

Section 3: Hazards Identification
Emergency Overview:Irritating to skin, eyes and respiratory tract.
Primary Routes of Exposure:Ingestion, inhalation
Eye Contact:Causes slight to mild irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No information available on the physiological effects of ingestion. May be harmful if swallowed.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:no data
Autoignition Temperature:no data
Explosion Limits:no data
Extinguishing Medium:carbon dioxide, dry powder or foam
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store in a tightly sealed container. Keep in a cool, dry, well ventilated place.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:Handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:yellow powder
Molecular Weight:293.53
Melting Point:no data
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:not determined
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:strong oxidizing agents
Decomposition Products:carbon monoxide, carbon dioxide, palladium oxide and organic fumes

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory
SARA (Title 313):Title compound not listed
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

~98%

14267-08-4结构式

14267-08-4

文献:Biscoe, Mark R.; Fors, Brett P.; Buchwald, Stephen L. Journal of the American Chemical Society, 2008 , vol. 130, # 21 p. 6686 - 6687

~97%

14267-08-4结构式

14267-08-4

文献:Zhao, Qing; Li, Chengxi; Senanayake, Chris H.; Tang, Wenjun Chemistry - A European Journal, 2013 , vol. 19, # 7 p. 2261 - 2265

~90%

14267-08-4结构式

14267-08-4

文献:Graaf, Wim de; Boersma, Jaap; Smeets, Wilberth J. J.; Spek, Anthony L.; Koten, Gerard van Organometallics, 1989 , vol. 8, p. 2907 - 2917

~97%

14267-08-4结构式

14267-08-4

文献:Jung, Miso; Suzaki, Yuji; Saito, Takashi; Shimada, Kyoichi; Osakada, Kohtaro Polyhedron, 2012 , vol. 40, # 1 p. 168 - 174

~%

14267-08-4结构式

14267-08-4

文献:Inorganic Chemistry, , vol. 31, p. 1090 - 1095

~%

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14267-08-4

文献:Polyhedron, , vol. 19, # 8 p. 959 - 963

~%

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14267-08-4

文献:Inorganica Chimica Acta, , vol. 188, p. 25 - 32

~%

14267-08-4结构式

14267-08-4

文献:Inorganica Chimica Acta, , vol. 198 - 200, p. 187 - 192

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