N,N'-二苯基-N,N'-(3-甲基苯基)-1,1'-联苯-4,4'-二胺, 99.9%,N,N'-Bis(3-methylphenyl)-N,N'-Bis(phenyl)benzidine

产品编号:西域试剂-WR356451| CAS NO:65181-78-4| MDL NO:MFCD00144965| 分子式:C38H32N2| 分子量:516.67

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货号 包装 价格 库存与货期 购买量 操作
西域试剂-WR356451
84.00 杭州 北京(现货)
西域试剂-WR356451
136.00 杭州 北京(现货)
西域试剂-WR356451
533.00 杭州 北京(现货)

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产品名称N,N'-二苯基-N,N'-(3-甲基苯基)-1,1'-联苯-4,4'-二胺, 99.9%
英文名称N,N'-Bis(3-methylphenyl)-N,N'-Bis(phenyl)benzidine
CAS编号65181-78-4
产品熔点169°C
产品沸点680.1±55.0 °C at 760 mmHg
产品密度1.1±0.1 g/cm3
产品闪点303.1±19.3 °C
精确质量516.256531
PSA6.48000
LogP11.94
外观性状固体
蒸气压0.0±2.1 mmHg at 25°C
折射率1.671
溶解性水溶性:不溶
稳定性

远离氧化物。

储存条件

存放在密封容器内,并放在阴凉,干燥处。储存的地方必须远离氧化剂。

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符号 GHS09
GHS09
危害声明 H411
警示性声明 P273
个人防护装备 Eyeshields;Gloves
危害码 (欧洲) N
风险声明 (欧洲) R36/37/38
安全声明 (欧洲) S26-S36/37/39-S61
危险品运输编码 3077
海关编码 2921590090
Name: N N -Diphenyl-N N -Di-M-Tolyl-Benzidine Material Safety Data Sheet
Synonym: N,N'-Diphenyl-N,N'-bis(3-methylphenyl)-(1,1'-diphenyl)-4,4'-diamine
CAS: 65181-78-4
Section 1 - Chemical Product MSDS Name:N N -Diphenyl-N N -Di-M-Tolyl-Benzidine Material Safety Data Sheet
Synonym:N,N'-Diphenyl-N,N'-bis(3-methylphenyl)-(1,1'-diphenyl)-4,4'-diamine

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
65181-78-4 N,N'-Diphenyl-N,N'-di-m-tolylbenzidine 100 413-810-8
Hazard Symbols: N
Risk Phrases: 51/53

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use dry chemical, carbon dioxide, or halon extinguisher.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits CAS# 65181-78-4: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Crystals
Color: yellowish-white
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 168 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density:
Molecular Formula: C38H32N2
Molecular Weight: 516.2374

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, various hydrocarbons.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 65181-78-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
N,N'-Diphenyl-N,N'-di-m-tolylbenzidine - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: N
Risk Phrases:
R 51/53 Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 65181-78-4: No information available.
Canada
CAS# 65181-78-4 is listed on Canada's NDSL List.
CAS# 65181-78-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 65181-78-4 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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