四氯双（四氢呋喃）锆, 99%|Tetrachlorobis(tetrahydrofuran)zirconium|cas:21959-01-3|西域试剂

四氯双（四氢呋喃）锆, 99%,Tetrachlorobis(tetrahydrofuran)zirconium

产品编号：西域试剂-WR361697| CAS NO：21959-01-3| MDL NO：MFCD00145367| 分子式：C₈H₁₆Cl₄O₂Zr| 分子量：377.25

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货号	包装	价格	库存与货期	购买量	操作
西域试剂-WR361697		￥677.00	杭州北京（现货）

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英文名称	Tetrachlorobis(tetrahydrofuran)zirconium
CAS编号	21959-01-3
产品熔点	175-177 °C(lit.)
精确质量	373.89500
PSA	18.46000
LogP	4.35160
蒸气压	152mmHg at 25°C
稳定性	如果遵照规格使用和储存则不会分解避免接触氧化物，水分
储存条件	0-6 ℃ 干性的保护气体下处置，保持贮藏器密封放入紧密的贮藏器内，储存在阴凉，干燥的地方

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符号	GHS02, GHS05, GHS07
信号词	Danger
危害声明	H228-H302 + H312 + H332-H314
警示性声明	P210-P280-P305 + P351 + P338-P310
个人防护装备	Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
危害码 (欧洲)	C:Corrosive;
风险声明 (欧洲)	R20/21/22;R34
安全声明 (欧洲)	S22-S26-S36/37/39-S45
危险品运输编码	UN 2925 4.1/PG 2
WGK德国	3
包装等级	II
危险类别	8

Name:	Tetrachlorobis(tetrahydrofuran)zirconium Material Safety Data Sheet
Synonym:	Zirconium(IV) chloride tetrahydrofura
CAS:	21959-01-3

Section 1 - Chemical Product MSDS Name:Tetrachlorobis(tetrahydrofuran)zirconium Material Safety Data Sheet
Synonym:Zirconium(IV) chloride tetrahydrofura

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
21959-01-3	Tetrachlorobis(tetrahydrofuran)zirconi		unlisted

Hazard Symbols: C
Risk Phrases: 20/21/22 34

Section 3 - HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed. Causes burns.Air sensitive.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Harmful if absorbed through the skin. Causes skin burns.
Ingestion:
Harmful if swallowed. Causes gastrointestinal tract burns.
Inhalation:
Harmful if inhaled. Causes chemical burns to the respiratory tract.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid immediately. Wash mouth out with water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Corrosives area. Store under nitrogen.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 21959-01-3: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 175 - 177 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C8H16Cl4O2Zr
Molecular Weight: 377.1428

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, exposure to air, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, alcohols, amines, acids.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 21959-01-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Tetrachlorobis(tetrahydrofuran)zirconium - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 21959-01-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 21959-01-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 21959-01-3 is not listed on the TSCA inventory.
It is for research and development use only.

SECTION 16 - ADDITIONAL INFORMATION
N/A