氟化钆(III), 无水, 粉末, 99.9% metals basis,Gadolinium(III) fluoride

产品编号:西域试剂-WR362333| CAS NO:13765-26-9| MDL NO:MFCD00016113| 分子式:GdF3| 分子量:214.25

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西域试剂-WR362333
73.00 杭州 北京(现货)
西域试剂-WR362333
241.00 杭州 北京(现货)
西域试剂-WR362333
644.00 杭州 北京(现货)
西域试剂-WR362333
1298.00 杭州 北京(现货)
西域试剂-WR362333
5044.00 杭州 北京(现货)

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产品名称氟化钆(III), 无水, 粉末, 99.9% metals basis
英文名称Gadolinium(III) fluoride
CAS编号13765-26-9
产品熔点1231°C
产品沸点19.5ºC at 760 mmHg
产品密度7.1
精确质量101.95100
LogP1.26060
外观性状白色结晶固体
稳定性

常温常压下稳定

避免的物料 酸 。不溶于冷水,微溶于热的氢氟酸中。
储存条件

常温密闭,阴凉通风干燥

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符号 GHS07
GHS07
信号词 Warning
危害声明 H315-H319-H335
警示性声明 P305 + P351 + P338
个人防护装备 dust mask type N95 (US);Eyeshields;Gloves
危害码 (欧洲) Xi: Irritant;
风险声明 (欧洲) R36/37/38
安全声明 (欧洲) S26-S36
危险品运输编码 UN 3288 6.1/PG 3
WGK德国 3
包装等级 III
危险类别 6.1

Section 1: Product Identification
Chemical Name:Gadolinium (III) fluoride, anhydrous (99.9%-Gd) (REO)
CAS Registry Number:13765-26-9
Formula:GdF3
EINECS Number:237-369-4
Chemical Family:metal halide
Synonym:Gadolinium trifluoride

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound13765-26-9100%2.5mg/m3 (as F)2.5mg/m3 (as F)

Section 3: Hazards Identification
Emergency Overview:Irritating to the respiratory tract, skin and eyes. May be harmful if swallowed.
Primary Routes of Exposure:Contact with skin and eyes. Inhalation of dust.
Eye Contact:Causes irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Irritating to skin, eyes and respiratory tract.
Toxicity reduced to the extent that this compound is relatively insoluble. In large amounts may cause vomiting,
Ingestion:
abdominal pain and diarrhea.
Irritating to skin, eyes and respiratory tract. Fluoride poisoning may cause nausea, vomiting, diarrhea,
Acute Health Affects:
weakness, coma, and respiratory paralysis.
Chronic Health Affects:Prolonged exposure to hydrolysable fluorine compounds can cause deterioration of bone and tooth structure.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Apply calcium gluconate jelly
Skin Exposure:
or water soluble calcium salts as antidote. Seek medical assistance.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:None. Material is non-flammable.
Special Fire Fighting Procedures:No special fire fighting procedures required.
Hazardous Combustion andnone
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with powdered sodium bicarbonate, lime, or calcium carbonate and swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store solid in a tightly sealed container.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
Respirator:
requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:white pwdr.
Molecular Weight:214.25
Melting Point:no data
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:none
Decomposition Products:none

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

~%

13765-26-9结构式

13765-26-9

文献:Gmelin Handbook: Sc: MVol.C3, 6.2.2.1.3, page 35 - 36 Full Text Show Details Th. Goldschmidt A.-G. Patent: DE1169907 , 1964 ; C. A., 1964 , vol. 61, p. 3965

~%

13765-26-9结构式

13765-26-9

文献:Zhurnal Neorganicheskoi Khimii, , vol. 12, p. 449 - 450 Zhurnal Neorganicheskoi Khimii, , vol. 12, p. 851 - 856 Sc: MVol.C3, 6.2.2.1.10, page 39 - 39
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