碘化钴, 99.5% trace metals basis,Cobalt(II) iodide

产品编号:西域试剂-WR363259| CAS NO:15238-00-3| MDL NO:MFCD00016030| 分子式:CoI2| 分子量:312.74

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货号 包装 价格 库存与货期 购买量 操作
西域试剂-WR363259
139.00 杭州 北京(现货)
西域试剂-WR363259
460.00 杭州 北京(现货)
西域试剂-WR363259
1726.00 杭州 北京(现货)

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英文名称Cobalt(II) iodide
CAS编号15238-00-3
产品熔点515ºC
产品沸点570ºC
产品密度5.68
产品闪点570ºC vac.
精确质量312.74200
LogP1.77140
外观性状powder
溶解性每100毫升水中的溶解克数: 203g/20℃
稳定性

有两种变体。(1)αCoI2。黑色六方晶体。易吸水,在空气中呈墨绿色。相对密度5.68。熔点515℃(高真空)。沸点570℃(高真空)。易溶于水、乙醇和丙酮。水溶液呈桃红色至红色。由钴粉在碘化氢气流中加热至400~500℃而得。(2)βCoI2。黄色针状晶体。相对密度5.45(25℃)。易吸水,在潮湿空气中形成绿色滴液。水溶液加热时变为玫瑰红色。加热至400℃时变黑,并转变成αCoI2。由αCoI2在高真空升华而得。六水合物为棕红色六方晶体,有吸水性,相对密度2.90,加热大于27℃时开始脱水,在130℃时变成无水物,见光或曝置于空气中放出碘,由碳酸钻或氢氧化钴溶于氢碘酸而得。

储存条件

常温密闭避光,通风干燥惰性气体下

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化学品安全说明书(MSDS)

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质检证书(COA)

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符号 GHS07
GHS07
信号词 Warning
危害声明 H302 + H312 + H332-H315-H319-H335
警示性声明 P261-P280-P305 + P351 + P338
个人防护装备 dust mask type N95 (US);Eyeshields;Gloves
危害码 (欧洲) Xn
风险声明 (欧洲) R20/21/22;R36/37/38
安全声明 (欧洲) S26;S36
危险品运输编码 NONH for all modes of transport
WGK德国 3

Section 1: Product Identification
Chemical Name:Cobalt (II) iodide, anhydrous, 99.5%
CAS Registry Number:15238-00-3
Formula:CoI2
EINECS Number:239-283-2
Chemical Family:metal halide
Synonym:Cobaltic iodide

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound15238-00-3100%0.02mg/m3 (as Co)no data

Section 3: Hazards Identification
Irritating to skin, eyes and respiratory tract. May be harmful if swallowed. Prolonged exposure to iodide salts
Emergency Overview:
may produce a mild toxic syndrome known as iodism. Limited evidence of a carcinogenic effect.
Primary Routes of Exposure:Contact with skin and eyes. Inhalation of dust.
Eye Contact:Contact with eyes causes irritation, redness, and pain.
Skin Contact:Causes irritation to skin. Symptoms include redness, itching, and pain, pimples, boils, hives and blisters.
Inhalation:Causes irritation to the respiratory tract. Symptoms may include coughing and shortness of breath.
Ingestion:Large oral doses may cause irritation to the gastrointestinal tract
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Limited evidence of a carcinogenic effect. Chronic ingestion of iodides may produce iodism. Symptoms include
Chronic Health Affects:skin rash, running nose, headache and irritation of mucous membranes. Cobalt may cause goiter and reduced
thyroid activity, dermatitis, kidney, heart and lung damage.
NTP:No
IARC:Yes
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:none required
If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
Special Fire Fighting Procedures:
breathing apparatus and full protective clothing.
Hazardous Combustion andnone
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
To avoid raising dust, small spills may be mixed with diatomaceous earth, sand, vermiculite or other suitable
Spill and Leak Procedures:
inert material and swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store solid in a tightly sealed container.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear appropriate chemical resistant gloves and protective clothing.
Ventilation:If possible, handle the material in an efficient fume hood.
If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
Respirator:
requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:-60 mesh black pwdr.
Molecular Weight:312.74
Melting Point:515° (vac.)
Boiling Point:570°C (vac.)
Vapor Pressure:no data
Specific Gravity:5.68
Odor:none
Solubility in Water:

SECTION 10: Stability and Reactivity
Stability:hygroscopic
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:contact with moisture
Incompatibility:Halogens, oxidizing agents and active metals
Decomposition Products:none

SECTION 11: Toxicological Information
RTECS Data:No specific information available on this product.
Carcinogenic Effects:Possible carcinogen (as Co)
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Listed in the TSCA inventory.
SARA (Title 313):Title compound: See category N096 for reporting.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

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