氯化亚铁,四水合物, 99.98% metals basis,Iron(II) chloride tetrahydrate
产品编号:西域试剂-WR363635| CAS NO:13478-10-9| MDL NO:MFCD00149709| 分子式:FeCl2·4H2O| 分子量:198.81
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产品名称 | 氯化亚铁,四水合物, 99.98% metals basis |
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英文名称 | Iron(II) chloride tetrahydrate |
CAS编号 | 13478-10-9 |
产品熔点 | 105 °C |
产品沸点 | 1026 °C |
产品密度 | 1.93 |
精确质量 | 197.91500 |
PSA | 36.92000 |
LogP | 1.11930 |
外观性状 | 淡绿色或蓝色-绿色晶体 |
蒸气压 | 10 mm Hg ( 693 °C) |
溶解性 | soluble |
稳定性 | 1.常温常压下稳定 2.避免的物料 氧化物。易潮解。在空气中易被氧化。溶于水和乙醇。微溶于丙酮,溶于乙醇,易溶于水。 |
储存条件 | 常温密闭,阴凉通风干燥 |
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化学品安全说明书(MSDS)
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相关产品
符号 |
![]() ![]() GHS05, GHS07 |
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信号词 | Danger |
危害声明 | H302-H314 |
警示性声明 | P280-P305 + P351 + P338-P310 |
个人防护装备 | dust mask type N95 (US);Eyeshields;Gloves |
危害码 (欧洲) | C:Corrosive; |
风险声明 (欧洲) | R22;R34 |
安全声明 (欧洲) | S26-S39-S45-S36/37/39 |
危险品运输编码 | UN 3260 8/PG 3 |
WGK德国 | 1 |
RTECS号 | NO5600000 |
包装等级 | III |
危险类别 | 8 |
海关编码 | 28273300 |
Synonym:Ferrous chloride tetrahydrat Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 22 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes, respiratory system and skin.The toxicological properties of this material have not been fully investigated.Hygroscopic (absorbs moisture from the air).Air sensitive. Potential Health Effects Eye: Contact with eyes may cause severe irritation, and possible eye burns. Skin: Exposure may cause irritation and possible burns. Ingestion: May cause severe gastrointestinal tract irritation with nausea, vomiting and possible burns. Acute exposure to excessive levels of ferrous compounds can cause liver and kidney damage. May cause CNS irritation. Inhalation: May cause respiratory tract irritation. Chronic: Chronic ingestion may cause effects similar to those of acute ingestion. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Antidote: The use of Deferoxamine as a chelating agent should be determined only by qualified medical personnel. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Substance is noncombustible. Extinguishing Media: Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 13478-10-9: Belgium - TWA: (listed as iron salts (soluble)): 1 mg/m3 VLE (as Malaysia: (listed as iron salts (soluble)): 1 mg/m3 TWA (as Fe) Netherlands: (listed as iron salts (soluble)): 1 mg/m3 MAC (as Fe Spain: (listed as iron salts (soluble)): 1 mg/m3 VLA-ED (as Fe) Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: light green Odor: Not available. pH: Not available. Vapor Pressure: 10 mm Hg @ 693 deg Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: Not available. Autoignition Temperature: Not applicable. Flash Point: Not applicable. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: > 150 deg C Solubility in water: 1600g/l (10C) in H2O Specific Gravity/Density: Not available. Molecular Formula: FeCl2.4H2O Molecular Weight: 198.8066 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, exposure to moist air or water. Incompatibilities with Other Materials: Ethylene oxide, potassium,sodium, strong oxidizing agents, ozonides, metal halides.. Hazardous Decomposition Products: Hydrogen chloride, oxides of iron. Hazardous Polymerization: Will not occur. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 13478-10-9: NO5600000 LD50/LC50: Not available. Carcinogenicity: Iron (II) chloride - Not listed by ACGIH, IARC, or NTP. Other: See actual entry in RTECS for complete information. Section 12 - ECOLOGICAL INFORMATION Ecotoxicity: Water danger/protection: WGK1 Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 22 Harmful if swallowed. R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 13478-10-9: 1 Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 13478-10-9 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 13478-10-9 is not on the TSCA Inventory because it is a hydrate. It is considered to be listed if the CAS number for the anhydrous form is on the inventory (40CFR720.3(u)(2)). SECTION 16 - ADDITIONAL INFORMATION N/A |