1,2-双(2S,5S)-二乙基环丁膦烷苯(环辛二烯)铑三氟甲磺酸盐, 99%,1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonat

产品编号:西域试剂-WR363979| CAS NO:142184-30-3| MDL NO:MFCD00269861| 分子式:C31H48F3O3P2RhS| 分子量:722.635

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货号 包装 价格 库存与货期 购买量 操作
西域试剂-WR363979
1221.00 杭州 北京(现货)
西域试剂-WR363979
2184.00 杭州 北京(现货)
西域试剂-WR363979
3484.00 杭州 北京(现货)

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英文名称1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonat
CAS编号142184-30-3
产品沸点254.2±35.0 °C at 760 mmHg
产品密度1.6±0.1 g/cm3
产品闪点107.5±25.9 °C
精确质量185.979248
PSA39.64000
LogP2.44
蒸气压0.0±0.5 mmHg at 25°C
折射率1.617
稳定性

如果遵照规格使用和储存则不会分解,未有已知危险反应

避免氧化物
储存条件

密封,在4ºC下保存

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符号 GHS07
GHS07
信号词 Warning
危害声明 H315-H319-H335
警示性声明 P261-P305 + P351 + P338
个人防护装备 dust mask type N95 (US);Eyeshields;Gloves
危害码 (欧洲) Xi
风险声明 (欧洲) 36/37/38
安全声明 (欧洲) S24/25
危险品运输编码 NONH for all modes of transport

Section 1: Product Identification
(+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(1,5-cyclooctadiene)rhodium (I)
Chemical Name:
trifluoromethanesulfonate, 98+% (S,S)-Et-DUPHOS-Rh
CAS Registry Number:142184-30-3
Formula:Rh(C8H12)(C22H36P2)+ CF3SO3-
EINECS Number:none
Chemical Family:organometallic complex
Synonym:none

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound142184-30-3100%2.5mg/m3 (as F)2.5mg/m3 (as F)

Section 3: Hazards Identification
Emergency Overview:Irritating to skin, eyes and respiratory tract.
Primary Routes of Exposure:Ingestion
Eye Contact:Causes irritation to the eyes
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No information is available on the physiological effects of ingestion.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:none
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, dry powder or foam
Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus
Special Fire Fighting Procedures:
and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
The material will degrade on prolonged exposure to air. Store cold, under an inert atmosphere of nitrogen or
Handling and Storage:argon. Keep bottle tightly sealed and away from heat and direct sunlight. For prolonged storage keep material
refrigerated.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:If possible, handle the material in an efficient fume hood.
If ventilation is not available, a respirator should be worn. The use of respirators requires a Respiratory
Respirator:
Protection program to be in compliance with 29 CFR 1910.134.
Ventilation:If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:orange xtl.
Molecular Weight:722.63
Melting Point:decomposes
Boiling Point:decomposes
Vapor Pressure:not applicable
Specific Gravity:no data
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air sensitive (store cold)
Hazardous Polymerization:none
Conditions to Avoid:contact with air. This material may degrade on prolonged exposure to air and moisture.
Incompatibility:strong oxidizing agents
Decomposition Products:carbon dioxide, carbon monoxide, phosphorus pentoxide, organic fumes and fluorinated byproducts.

SECTION 11: Toxicological Information
RTECS Data:No data available
Carcinogenic Effects:No data available
Mutagenic Effects:No data available
Tetratogenic Effects:No data available

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:not listed on the TSCA inventory
SARA (Title 313):not regulated by Title 313
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

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