硫化镍(II), 99.00,Nickel(II)sulfide(99.9%-Ni)

产品编号:西域试剂-WR365441| CAS NO:16812-54-7| MDL NO:MFCD00016266| 分子式:SNI| 分子量:90.76000000000001

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货号 包装 价格 库存与货期 购买量 操作
西域试剂-WR365441
73.00 杭州 北京(现货)
西域试剂-WR365441
273.00 杭州 北京(现货)
西域试剂-WR365441
977.00 杭州 北京(现货)

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英文名称Nickel(II)sulfide(99.9%-Ni)
CAS编号16812-54-7
产品熔点797ºC
产品密度5.3 g/cm3
精确质量89.907417
PSA25.30000
外观性状Powder
蒸气压12600mmHg at 25°C
溶解性0.00036g/100mL H2O (18°C) [CRC10]
稳定性

常温常压下稳定

避免的物料: 氧化物 酸.

相对密度5.3~5.65(α);5.0~5.6(β);5.34(γ,30℃)。熔点797℃(α);810℃(β);γ-NiS在396℃时转变为βNiS。α-NiS溶于盐酸,在空气中转变成Ni(OH)S。β-NiS在2mol/L HCl中煮沸,迅速溶解。它们均溶于硝酸和王水。

储存条件

常温密闭避光,通风干燥

相关文档

化学品安全说明书(MSDS)

下载MSDS

质检证书(COA)

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危害码 (欧洲) T,N
风险声明 (欧洲) 43-49-50/53
安全声明 (欧洲) 53-45-61
危险品运输编码 UN 2811

Section 1: Product Identification
Chemical Name:Nickel (II) sulfide (99.9%-Ni)
CAS Registry Number:16812-54-7
Formula:Ni3S2/NiS
EINECS Number:240-841-2
Chemical Family:metal chalcogenides
Synonym:Nickel monosulfide

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound16812-54-7100%0.2mg/m31mg/m3

Section 3: Hazards Identification
Irritating to skin, eyes and respiratory tract. May cause sensitization by skin contact. May cause cancer by
Emergency Overview:
inhalation.
Primary Routes of Exposure:Ingestion, inhalation, skin and eyes
Eye Contact:Dust causes moderate irritation of the eyes.
Skin Contact:Causes slight irritation of the skin. Prolonged contact with nickel salts may lead to dermatitis.
Inhalation:Inhalation of dust will lead to irritation of the respiratory tract. May cause cancer by inhalation.
Gastric juices may cause release of toxic hydrogen sulfide, causing, nausea, dizziness, pulmonary edema,
Ingestion:
death.
Acute Health Affects:Irritating to skin, eyes and respiratory tract. May cause sensitization by skin contact.
Long term exposure to nickel and nickel compounds may lead to skin irritation and dermatitis. May cause
Chronic Health Affects:
cancer.
NTP:Yes
IARC:Yes
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:no data
Explosion Limits:no data
Extinguishing Medium:carbon dioxide or dry powder
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self- contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit irritating fumes of hydrogen sulfide and sulfur dioxide.
Decomposion Products:
Dust may form explosive mixtures with air. Contact with acids gives off hydrogen sulfide, a toxic and
Unusual Fire or Explosion Hazards:
flammable gas.

SECTION 6: Accidental Release Measures
In the case of a spill, the fine powder should be covered with dry sodium carbonate or dolomite in order to
Spill and Leak Procedures:
reduce the formation of dust. Sweep up the mixture.

SECTION 7: Handling and Storage
Store in a tightly sealed container. Exposure to the atmosphere may lead to release of toxic hydrogen sulfide
Handling and Storage:
gas. Empty containers may retain product residues that evolve toxic gases.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear appropriate chemical resistant gloves and protective clothing.
Ventilation:If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of a respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:-200 mesh black pwdr.
Molecular Weight:not applicable
Melting Point:797°
Boiling Point:no data
Vapor Pressure:not applicable
Specific Gravity:5.3-5.65
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:Contact of dust cloud with an ignition source.
Incompatibility:none
Decomposition Products:hydrogen sulfide, sulfur dioxide, and metal oxides.

SECTION 11: Toxicological Information
RTECS Data:No specific information available on this product.
Carcinogenic Effects:Tumorigen
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Listed in the TSCA inventory.
SARA (Title 313):Title compound: see category code N495 for reporting.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

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