无水氟化镓(III), 999.00,Gallium(III) fluoride

产品编号:西域试剂-WR365482| CAS NO:7783-51-9| MDL NO:MFCD00011021| 分子式:F3Ga| 分子量:126.72

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货号 包装 价格 库存与货期 购买量 操作
西域试剂-WR365482
158.00 杭州 北京(现货)
西域试剂-WR365482
513.00 杭州 北京(现货)
西域试剂-WR365482
1575.00 杭州 北京(现货)

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英文名称Gallium(III) fluoride
CAS编号7783-51-9
产品熔点800ºC
产品沸点19.5ºC at 760mmHg
产品密度4.47 g/mL at 25 °C(lit.)
产品闪点1000°C
精确质量125.92100
LogP0.87980
外观性状无色针状结晶
稳定性

如果遵照规格使用和储存则不会分解

在100g水中的溶解度为0.002g。稍溶于碱金属氢氧化物水溶液中,但是难溶于稀酸。在空气中稳定,不发生变化。避免接触酸,水分/潮湿

储存条件

干性的保护气体下处置,

保持贮藏器密封

放入紧密的贮藏器内,储存在阴凉,干燥的地方

相关文档

化学品安全说明书(MSDS)

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质检证书(COA)

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符号 GHS07
GHS07
信号词 Warning
危害声明 H302 + H312 + H332
警示性声明 P261-P280-P301 + P312 + P330
个人防护装备 dust mask type N95 (US);Eyeshields;Gloves
危害码 (欧洲) Xn,Xi
风险声明 (欧洲) 20/21/22
安全声明 (欧洲) 36
危险品运输编码 UN3260
WGK德国 3
包装等级 III

Section 1: Product Identification
Chemical Name:Gallium (III) fluoride trihydrate, 99.5%
CAS Registry Number:7783-51-9
Formula:GaF3.3H2O
EINECS Number:232-004-5
Chemical Family:metal halide
Synonym:Gallium trifluoride

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound7783-51-9100%2.5mg/m3 (as F)2.5mg/m3 (as F)

Section 3: Hazards Identification
Emergency Overview:Irritating to the respiratory tract, skin and eyes. May be harmful if swallowed.
Primary Routes of Exposure:Ingestion, inhalation, skin, eyes
Eye Contact:Irritating to the eyes. may cause serious eye damage. Effects may not immediately appear.
Skin Contact:Prolonged contact with skin causes irritation.
Inhalation:Dust or hydrofluoric acid fumes cause severe irritation to the respiratory tract.
Ingestion:May cause salivation, nausea, vomiting, diarrhea, and painful abdominal burns.
Irritating to skin, eyes and respiratory tract. Fluoride poisoning may cause nausea, vomiting, diarrhea,
Acute Health Affects:
weakness, coma, and respiratory paralysis.
Product contains fluorine which, under certain conditions of use, decomposition or metabolism, may generate
Chronic Health Affects:fluoride ion causing nausea, vomiting, labored breathing, hypocalcaemia, deterioration of bone and tooth
structure and kidney and liver damage.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Apply calcium gluconate jelly
Skin Exposure:
or water soluble calcium salts as antidote. Seek medical assistance.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:none required
If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
Special Fire Fighting Procedures:
breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit corrosive hydrogen fluoride fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
To avoid raising dust, small spills can be mixed with powdered sodium bicarbonate, lime, or calcium carbonate
Spill and Leak Procedures:
and swept up.

SECTION 7: Handling and Storage
Store material in a tightly sealed bottle away from moisture. If possible, handle material in an efficient fume
Handling and Storage:
hood. Prolonged exposure to the atmosphere may lead to degradation of the product.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear appropriate chemical resistant gloves and protective clothing.
Ventilation:If possible, handle the material in an efficient fume hood.
If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
Respirator:
requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:white xtl.
Molecular Weight:126.72 (180.76)
Melting Point:no data
Boiling Point:no data
Vapor Pressure:not applicable
Specific Gravity:no data
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:contact with moisture
Incompatibility:Mineral acids and active metals
Decomposition Products:with moisture: hydrofluoric acid and gallium oxides

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Listed in the TSCA inventory.
SARA (Title 313):Title compound not listed
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

~%

7783-51-9结构式

7783-51-9

文献:Thermochimica Acta, , vol. 363, # 1-2 p. 55 - 59

~%

7783-51-9结构式

7783-51-9

文献:Gupta, O. D.; Kirchmeier, Robert L.; Shreeve, Jean'ne M. Inorganic Chemistry, 1990 , vol. 29, p. 573 - 574

~%

7783-51-9结构式

7783-51-9

文献:Zeitschrift fur Anorganische und Allgemeine Chemie, , vol. 623, # 4 p. 579 - 582
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