2,4,6-三甲基苯硫酚, 99%,2,4,6-Trimethylthiophenol
产品编号:西域试剂-WR370911| CAS NO:1541-10-2| MDL NO:MFCD00218475| 分子式:C9H12S| 分子量:152.26
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英文名称 | 2,4,6-Trimethylthiophenol |
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CAS编号 | 1541-10-2 |
产品熔点 | 142-143°C |
产品沸点 | 231.8ºC at 760mmHg |
产品密度 | 1.009g/cm3 |
产品闪点 | 91.3ºC |
精确质量 | 152.06600 |
PSA | 38.80000 |
LogP | 2.90050 |
蒸气压 | 0.0928mmHg at 25°C |
稳定性 | 如果遵照规格使用和储存则不会分解,未有已知危险反应,避免氧化物 |
储存条件 | 保持贮藏器密封、储存在阴凉、干燥的地方,确保工作间有良好的通风或排气装置 |
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风险声明 (欧洲) | R36/37/38 |
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安全声明 (欧洲) | S26-S36 |
海关编码 | 2930909090 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 20/21/22 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Harmful if absorbed through the skin. Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. Inhalation: Harmful if inhaled. May cause respiratory tract irritation. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 1541-10-2: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: colorless Odor: stench pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C9H12S Molecular Weight: 152 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, oxides of sulfur, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 1541-10-2 unlisted. LD50/LC50: Not available. Carcinogenicity: 2,4,6-Trimethylbenzene-1-thiol - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.* Hazard Class: 6.1 UN Number: 2810 Packing Group: III IMO Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2810 Packing Group: III RID/ADR Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2810 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. Safety Phrases: S 36/37 Wear suitable protective clothing and gloves. WGK (Water Danger/Protection) CAS# 1541-10-2: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 1541-10-2 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 1541-10-2 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
~84% ![]() 1541-10-2 |
文献:Societe Nationale Elf Aquitaine (Production) Patent: US5113019 A1, 1992 ; |
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文献:Blower, Philip J.; Dilworth, Jonathan R.; Hutchinson, John P.; Zubieta, Jon A. Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1985 , p. 1533 - 1542 |
~70% ![]() 1541-10-2 |
文献:Becht, Jean-Michel; Wagner, Alain; Mioskowski, Charles Journal of Organic Chemistry, 2003 , vol. 68, # 14 p. 5758 - 5761 |
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文献:Phosphorus, Sulfur and Silicon and the Related Elements, , vol. 68, # 1-4 p. 261 - 292 |
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文献:Synlett, , # 17 art. no. G25605ST, p. 2691 - 2693 |
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