碘化铵, AR,99.0%,Ammonium iodide
产品编号:西域试剂-WR372052| CAS NO:12027-06-4| MDL NO:MFCD00011424| 分子式:NH4I| 分子量:144.94
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产品名称 | 碘化铵, AR,99.0% |
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英文名称 | Ammonium iodide |
CAS编号 | 12027-06-4 |
产品熔点 | 551 °C |
产品沸点 | 69.4ºC at 760 mmHg |
产品密度 | 2.51 |
精确质量 | 144.938828 |
PSA | 3.24000 |
LogP | 1.32210 |
外观性状 | 白色结晶粉末 |
蒸气压 | 5990mmHg at 25°C |
折射率 | 1.7031 |
溶解性 | 不同温度(℃)时每100毫升水中的溶解克数: 155g/0℃;163g/10℃;172g/20℃;182g/30℃;191g/40℃ 209g/60℃;229g/80℃;250g/100℃ |
稳定性 | 1.具有潮解性和感光性,遇光和空气能析出游离碘而呈黄色甚至褐色。551℃升华。 2.碘化铵水溶液易被氧化分解,同时析出碘变为黄色。 |
储存条件 | 1.应贮存在阴凉、避光、干燥的库房内。瓶口必须密封。 2.运输时要防雨淋和日晒。装卸时要轻拿轻放,严禁振动、撞击。失火时,可用沙土、二氧化碳灭火器扑救。 |
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化学品安全说明书(MSDS)
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相关产品
符号 |
![]() GHS07 |
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信号词 | Warning |
危害声明 | H315-H319-H335 |
警示性声明 | P261-P305 + P351 + P338 |
个人防护装备 | dust mask type N95 (US);Eyeshields;Gloves |
危害码 (欧洲) | Xi: Irritant; |
风险声明 (欧洲) | R36/37/38 |
安全声明 (欧洲) | S26 |
危险品运输编码 | NONH for all modes of transport |
WGK德国 | 3 |
海关编码 | 2827600000 |
Synonym:None known Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Hygroscopic (absorbs moisture from the air).Air sensitive.Light sensitive.The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Chronic ingestion of iodides during pregnancy has resulted in fetal death, severe goiter, and cretinoid appearance of the newborn. Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Chronic: Chronic ingestion of iodides during pregnancy has resulted in fetal death, severe goiter, and cretinoid appearance of the newborn.. Prolonged exposure to iodides may produce iodism in sensitive individuals. Symptoms could include skin rash, running nose and headache. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Use water spray to cool fire-exposed containers. Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation. Place under an inert atmosphere. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Store protected from light. Handle under an inert atmosphere. Store protected from air. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Do not expose to air. Store protected from moisture. Store protected from light. Store under an inert atmosphere. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 12027-06-4: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Crystals Color: white to light yellow Odor: None reported. pH: 4.5-6.5, 5% aq. soln Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 551 deg C Autoignition Temperature: Not applicable. Flash Point: 405 deg C ( 761.00 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: 405 deg C Solubility in water: 1g/0.6ml Specific Gravity/Density: 2.5140g/cm3 Molecular Formula: H4IN Molecular Weight: 144.94 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, light, dust generation, exposure to air, excess heat, strong oxidants, exposure to moist air or water. Incompatibilities with Other Materials: Air, moisture, strong oxidizing agents. Hazardous Decomposition Products: Oxides of nitrogen, irritating and toxic fumes and gases, hydrogen iodide. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 12027-06-4 unlisted. LD50/LC50: Not available. Carcinogenicity: Ammonium iodide ((nh4)i) - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: Not regulated. Hazard Class: UN Number: Packing Group: IMO Shipping Name: Not regulated. Hazard Class: UN Number: Packing Group: RID/ADR Shipping Name: Not regulated. Hazard Class: UN Number: Packing group: Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. S 28A After contact with skin, wash immediately with plenty of water. S 37 Wear suitable gloves. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 12027-06-4: 1 Canada CAS# 12027-06-4 is listed on Canada's DSL List. CAS# 12027-06-4 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 12027-06-4 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A |