3-氟-4-硝基苯甲醚, 99%,3-Fluoro-4-nitroanisole
产品编号:西域试剂-WR374913| CAS NO:446-38-8| 分子式:C7H6FNO3| 分子量:171.13
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英文名称 | 3-Fluoro-4-nitroanisole |
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CAS编号 | 446-38-8 |
产品熔点 | 57.3ºC |
产品沸点 | 264.5±20.0 °C at 760 mmHg |
产品密度 | 1.3±0.1 g/cm3 |
产品闪点 | 113.7±21.8 °C |
精确质量 | 171.033173 |
PSA | 55.05000 |
LogP | 1.82 |
外观性状 | 固体;White to Orange to Green powder to crystal |
蒸气压 | 0.0±0.5 mmHg at 25°C |
折射率 | 1.522 |
储存条件 | Keep Cold |
相关文档
化学品安全说明书(MSDS)
下载MSDS质检证书(COA)
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危害码 (欧洲) | Xi: Irritant; |
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风险声明 (欧洲) | 34 |
安全声明 (欧洲) | 26-36/37/39-45 |
危险品运输编码 | 3261 |
包装等级 | Ⅱ |
海关编码 | 2909309090 |
Material Safety Data Sheet
Section1. Identification of the substance 3-Fluoro-4-nitroanisole Product Name: Synonyms:2-Fluoro-4-methoxy-1-nitrobenzene Section2. Hazards identification Harmful by inhalation, in contact with skin, and if swallowed.
H314:Causes severe skin burns and eye damage H335:May cause respiratory irritation H412:Harmful to aquatic life with long lasting effects P261:Avoid breathing dust/fume/gas/mist/vapours/spray Avoid release to the environment P273: P280:Wear protective gloves/protective clothing/eye protection/face protection P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing P310:Immediately call a POISON CENTER or doctor/physician Section3. Composition/information on ingredients. 3-Fluoro-4-nitroanisole Ingredient name: CAS number:446-38-8 Section4. First aid measures Immediately wash skin with copious amounts of water for at least 15 minutes while removing Skin contact: contaminated clothing and shoes. If irritation persists, seek medical attention. Eye contact:Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate flushing of the eyes by separating the eyelids with fingers. If irritation persists, seek medical attention. Inhalation:Remove to fresh air. In severe cases or if symptoms persist, seek medical attention. Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention. Ingestion: Section5. Fire fighting measures In the event of a fire involving this material, alone or in combination with other materials, use dry powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus should be worn. Section6. Accidental release measures Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national standards. Respiratory precaution:Wear approved mask/respirator Hand precaution:Wear suitable gloves/gauntlets Skin protection:Wear suitable protective clothing Eye protection:Wear suitable eye protection Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container for disposal. See section 12. Environmental precautions: Do not allow material to enter drains or water courses. Section7. Handling and storage Handling:This product should be handled only by, or under the close supervision of, those properly qualified in the handling and use of potentially hazardous chemicals, who should take into account the fire, health and chemical hazard data given on this sheet. Storage:Store in closed vessels. Section8. Exposure Controls / Personal protection Engineering Controls: Use only in a chemical fume hood. Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles. General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse. Section9. Physical and chemical properties Not specified Appearance: Boiling point:No data Melting point:No data Flash point:No data Density:No data Molecular formula:C7H6FNO3 Molecular weight:171.1 Section10. Stability and reactivity Conditions to avoid: Heat, flames and sparks. Materials to avoid: Oxidizing agents. Possible hazardous combustion products: Carbon monoxide, nitrogen oxides, hydrogen fluoride. Section11. Toxicological information No data. Section12. Ecological information No data. Section13. Disposal consideration Arrange disposal as special waste, by licensed disposal company, in consultation with local waste disposal authority, in accordance with national and regional regulations. Section14. Transportation information UN Number:UN3261 Class: 8 Packing group: II Proper shipping name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. (3-Fluoro-4-nitroanisole) Section15. Regulatory information No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302, or have known CAS numbers that exceed the threshold reporting levels established by SARA Title III, Section 313. SECTION 16 - ADDITIONAL INFORMATION N/A |
~99% ![]() 446-38-8 |
文献:Deiters, Emmanuel; Song, Bo; Chauvin, Anne-Sophie; Vandevyver, Caroline D. B.; Gumy, Frederic; Buenzli, Jean-Claude G. Chemistry - A European Journal, 2009 , vol. 15, # 4 p. 885 - 900 |
~81% ![]() 446-38-8 |
文献:Makosza, Mieczyslaw; Lemek, Tadeusz; Kwast, Andrzej; Terrier, Francois Journal of Organic Chemistry, 2002 , vol. 67, # 2 p. 394 - 400 |
~97% ![]() 446-38-8 |
文献:GLAXO GROUP LIMITED Patent: WO2006/2047 A2, 2006 ; Location in patent: Page/Page column 69 ; |
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文献:MERCK and CO., INC. Patent: WO2007/108968 A2, 2007 ; Location in patent: Page/Page column 38-39 ; |
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详细
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文献:Ouellet, Stephane G.; Bernardi, Anna; Angelaud, Remy; O'Shea, Paul D. Tetrahedron Letters, 2009 , vol. 50, # 27 p. 3776 - 3779 |
~% ![]() 446-38-8 |
文献:Kizner, T. A.; Shteingarts, V. D. Journal of Organic Chemistry USSR (English Translation), 1985 , vol. 21, # 11 p. 2173 - 2178 Zhurnal Organicheskoi Khimii, 1985 , vol. 21, # 11 p. 2376 - 2382 |
~% ![]() 446-38-8 |
文献:Jacquet, Jean-Pierre; Bouzard, Daniel; Cesare, Pierre Di; Dolnic, Nicolas; Massoudi, Massoud; Remuzon, Philippe Heterocycles, 1992 , vol. 34, # 12 p. 2301 - 2311 |
~55% ![]() 446-38-8 |
文献:Purrington, Suzanne T.; Woodard, Daniel L. Journal of Organic Chemistry, 1991 , vol. 56, # 1 p. 142 - 145 |
~% ![]() 446-38-8 |
文献:Kizner, T. A.; Shteingarts, V. D. Journal of Organic Chemistry USSR (English Translation), 1985 , vol. 21, # 11 p. 2173 - 2178 Zhurnal Organicheskoi Khimii, 1985 , vol. 21, # 11 p. 2376 - 2382 |
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