3-溴苄肼, 99%,3-Bromobenzhydrazide
产品编号:西域试剂-WR375638| CAS NO:39115-96-3| MDL NO:MFCD00007600| 分子式:C7H7BrN2O| 分子量:215.05
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英文名称 | 3-Bromobenzhydrazide |
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CAS编号 | 39115-96-3 |
产品熔点 | 155-156°C |
产品沸点 | 368.5ºC at 760 mmHg |
产品密度 | 1.6±0.1 g/cm3 |
产品闪点 | 176.7ºC |
精确质量 | 213.974167 |
PSA | 55.12000 |
LogP | 1.26 |
外观性状 | 固体;White to Almost white powder to crystal |
折射率 | 1.615 |
稳定性 | 常规情况下不会分解,没有危险反应 |
储存条件 | 密封、阴凉、干燥保存 |
相关文档
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相关产品
符号 |
![]() GHS07 |
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信号词 | Warning |
危害声明 | H315-H319-H335 |
警示性声明 | P261-P305 + P351 + P338 |
个人防护装备 | dust mask type N95 (US);Eyeshields;Gloves |
危害码 (欧洲) | Xi |
风险声明 (欧洲) | R36/37/38 |
安全声明 (欧洲) | S26-S36/37/39-S37/39 |
危险品运输编码 | NONH for all modes of transport |
海关编码 | 2928000090 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. Ingestion: The toxicological properties of this substance have not been fully investigated. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: In case of fire use water spray, dry chemical, carbon dioxide, or chemical foam. Autoignition Temperature: Not available. Flash Point: Not available. NFPA Rating: Not published. Explosion Limits, Lower: Not available. Upper: Not available. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29CFR 1910.134. Always use a NIOSH-approved respirator when necessary. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Appearance: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Vapor Density: Not available. Evaporation Rate: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 157 - 159 deg C Decomposition Temperature: Not available. Solubility: Not available. Specific Gravity/Density: Not available. Molecular Formula: C7H7BrN2O Molecular Weight: 215.06 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents, strong bases. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen bromide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 39115-96-3 unlisted. LD50/LC50: Not available. Carcinogenicity: 3-Bromobenzoic hydrazide - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. See actual entry in RTECS for complete information. Section 12 - ECOLOGICAL INFORMATION For further information, contact Fisher Scientific. Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION CDG/CPL IMO Not regulated as a hazardous material. IATA Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Canadian TDG No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 39115-96-3: Canada None of the chemicals in this product are listed on the DSL/NDSL list. WHMIS: Not available. CAS# 39115-96-3 is not listed on Canada's Ingredient Disclosure List. Exposure Limits US FEDERAL TSCA CAS# 39115-96-3 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
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文献:SEMICONDUCTOR ENERGY LABORATORY CO., LTD. Patent: EP1972625 A1, 2008 ; Location in patent: Page/Page column 19-20 ; |
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文献:Zaheer, Muhammad; Zia-Ur-Rehman, Muhammad; Rahman, Salma; Ahmed, Naveed; Chaudhary, Muhammad Nawaz Journal of the Chilean Chemical Society, 2012 , vol. 57, # 4 p. 1492 - 1496 |
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文献:Khan, Mahmood-Ul-Hassan; Hameed, Shahid; Yasin, Khawaja A.; Akhtar, Tashfeen; Khan, Khalid M. Monatshefte fur Chemie, 2010 , vol. 141, # 4 p. 479 - 484 |
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文献:Li, Liangjing; Ding, Hao; Wang, Baogang; Yu, Shichong; Zou, Yan; Chai, Xiaoyun; Wu, Qiuye Bioorganic and Medicinal Chemistry Letters, 2014 , vol. 24, # 1 p. 192 - 194 |
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文献:Angell, Richard M.; Angell, Tony D.; Bamborough, Paul; Brown, David; Brown, Murray; Buckton, Jacky B.; Cockerill, Stuart G.; Edwards, Chris D.; Jones, Katherine L.; Longstaff, Tim; Smee, Penny A.; Smith, Kathryn J.; Somers, Don O.; Walker, Ann L.; Willson, Malcolm Bioorganic and Medicinal Chemistry Letters, 2008 , vol. 18, # 1 p. 324 - 328 |
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