2-(Boc-氨基)呋喃, 98%,2-(Boc-amino)furan
产品编号:西域试剂-WR376333| CAS NO:56267-47-1| MDL NO:MFCD02682023| 分子式:C9H13NO3| 分子量:183.20
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产品名称 | 2-(Boc-氨基)呋喃, 98% |
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英文名称 | 2-(Boc-amino)furan |
CAS编号 | 56267-47-1 |
产品熔点 | 98ºC |
产品沸点 | 205.3±13.0 °C at 760 mmHg |
产品密度 | 1.1±0.1 g/cm3 |
产品闪点 | 78.0±19.8 °C |
精确质量 | 183.089539 |
PSA | 51.47000 |
LogP | 2.83 |
蒸气压 | 0.3±0.4 mmHg at 25°C |
折射率 | 1.513 |
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危害码 (欧洲) | Xi |
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风险声明 (欧洲) | R24/25 |
安全声明 (欧洲) | 24/25-45-36/37-26 |
海关编码 | 2932190090 |
Synonym:Furan-2-yl-carbamic acid tert-butyl este Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Not available. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: May cause respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 56267-47-1: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: off-white Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C9H13NO3 Molecular Weight: 183 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Acids, strong oxidizing agents. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide, acrid smoke and fumes, ammonia. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 56267-47-1 unlisted. LD50/LC50: Not available. Carcinogenicity: tert-Butyl N-(2-furyl)carbamate - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 56267-47-1: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 56267-47-1 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 56267-47-1 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
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文献:CELGENE CORPORATION; TRAVERSE, John, F.; FEIGELSON, Gregg, Brian; RUCHELMAN, Alexander, L.; LIU, Jihong; LIU, Hongfeng; MA, Chengjun; LIU, Danyang; ZHANG, Steven Patent: WO2014/18866 A1, 2014 ; Location in patent: Paragraph 00192; 00193 ; |
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文献:Tetrahedron, , vol. 65, # 33 p. 6720 - 6729 |
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文献:Helvetica Chimica Acta, , vol. 91, # 2 p. 187 - 208 |
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文献:Tetrahedron, , vol. 65, # 33 p. 6720 - 6729 |
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