4-氯茴香硫醚, 99%,4-Chlorothioanisole
产品编号:西域试剂-WR376903| CAS NO:123-09-1| MDL NO:MFCD00013643| 分子式:ClC6H4SCH3| 分子量:158.65
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产品名称 | 4-氯茴香硫醚, 99% |
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英文名称 | 4-Chlorothioanisole |
CAS编号 | 123-09-1 |
产品沸点 | 222.4±23.0 °C at 760 mmHg |
产品密度 | 1.2±0.1 g/cm3 |
产品闪点 | 90.0±19.8 °C |
精确质量 | 157.995697 |
PSA | 25.30000 |
LogP | 3.73 |
外观性状 | 液体;Colorless to Light yellow to Light orange clear liquid |
蒸气压 | 0.2±0.4 mmHg at 25°C |
折射率 | 1.588 |
稳定性 | 一、性质:该品为无色液体。 |
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符号 |
![]() GHS07 |
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信号词 | Warning |
危害声明 | H302 |
个人防护装备 | Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
危害码 (欧洲) | Xn:Harmful; |
风险声明 (欧洲) | R22 |
安全声明 (欧洲) | S23-S26-S36/37/39 |
危险品运输编码 | 2810 |
WGK德国 | 3 |
RTECS号 | WQ3840000 |
包装等级 | III |
危险类别 | 6.1(b) |
海关编码 | 2930909090 |
Synonym:4-Chlorothioanisol Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 22 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Harmful if swallowed. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. Inhalation: May cause respiratory tract irritation. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use extinguishing media most appropriate for the surrounding fire. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 123-09-1: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: Clear colourless liquid Odor: stench pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 168 - 169 deg C @ 760mmHg Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: 229 deg F ( 109.44 deg C) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: 1.2145g/cm3 @ 20C Molecular Formula: C7H7ClS Molecular Weight: 158.562 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Hydrogen chloride, carbon monoxide, oxides of sulfur, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 123-09-1: WQ3840000 LD50/LC50: CAS# 123-09-1: Draize test, rabbit, eye: 100 mg Mild; Oral, mouse: LD50 = 672 mg/kg; Oral, rat: LD50 = 400 mg/kg. Carcinogenicity: 4-Chlorophenyl methyl sulfide - Not listed by ACGIH, IARC, or NTP. Other: See actual entry in RTECS for complete information. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 22 Harmful if swallowed. Safety Phrases: WGK (Water Danger/Protection) CAS# 123-09-1: No information available. Canada CAS# 123-09-1 is listed on Canada's NDSL List. CAS# 123-09-1 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 123-09-1 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A |
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