2-甲氧羰基苯磺酰氯, 98%,Methyl 2-(chlorosulfonyl)benzoate

产品编号:西域试剂-WR381269| CAS NO:26638-43-7| MDL NO:MFCD00009797| 分子式:C8H7ClO4S| 分子量:234.66

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西域试剂-WR381269
47.00 杭州 北京(现货)
西域试剂-WR381269
111.00 杭州 北京(现货)
西域试剂-WR381269
348.00 杭州 北京(现货)
西域试剂-WR381269
1297.00 杭州 北京(现货)

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英文名称Methyl 2-(chlorosulfonyl)benzoate
CAS编号26638-43-7
产品熔点62-63 °C
产品沸点344.8±25.0 °C at 760 mmHg
产品密度1.4±0.1 g/cm3
产品闪点162.3±23.2 °C
精确质量233.975357
PSA68.82000
LogP1.97
外观性状固体
蒸气压0.0±0.8 mmHg at 25°C
折射率1.541
溶解性reacts
稳定性

如果遵照规格使用和储存则不会分解

避免接触水分/潮湿,氧化物,碱
储存条件

0-6℃

相关文档

化学品安全说明书(MSDS)

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危害码 (欧洲) C
风险声明 (欧洲) R14;R29;R34
安全声明 (欧洲) S45-S36/37/39-S30-S26-S22
危险品运输编码 3261
包装等级 III
危险类别 8
海关编码 2916399090
Name: Methyl 2-(chlorosulfonyl)benzoate tech. 90% Material Safety Data Sheet
Synonym: CB
CAS: 26638-43-7
Section 1 - Chemical Product MSDS Name:Methyl 2-(chlorosulfonyl)benzoate tech. 90% Material Safety Data Sheet
Synonym:CB

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
26638-43-7 Methyl 2-(chlorosulfonyl)benzoate, tec 90.0 unlisted
Hazard Symbols: C
Risk Phrases: 34

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Causes burns.Moisture sensitive.Corrosive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns.
Inhalation:
May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation.
If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Antidote: None reported.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Do NOT use water directly on fire. Use foam, dry chemical, or carbon dioxide.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Use with adequate ventilation. Discard contaminated shoes.
Storage:
Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep refrigerated. (Store below 4C/39F.) Keep containers tightly closed.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 26638-43-7: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: Not available.
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 59.00 - 64.00 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C8H7ClO4S
Molecular Weight: 234.65

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, oxides of sulfur, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 26638-43-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Methyl 2-(chlorosulfonyl)benzoate, tech. - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
Other No information available.

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: CORROSIVE SOLID, N.O.S.*
Hazard Class: 8
UN Number: 1759
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing group: III

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 26638-43-7: No information available.
Canada
CAS# 26638-43-7 is listed on Canada's NDSL List.
CAS# 26638-43-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 26638-43-7 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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文献:Bayer Aktiengesellschaft Patent: US4725303 A1, 1988 ;

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文献:Waser, Jerome; Gaspar, Boris; Nambu, Hisanori; Carreira, Erick M. Journal of the American Chemical Society, 2006 , vol. 128, # 35 p. 11693 - 11712

~93%

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文献:Kim; Ko Synthesis, 1992 , # 12 p. 1203 - 1204

~%

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文献:Waser, Jerome; Gaspar, Boris; Nambu, Hisanori; Carreira, Erick M. Journal of the American Chemical Society, 2006 , vol. 128, # 35 p. 11693 - 11712

~%

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文献:Maumee Devel.Co. Patent: US2667503 , 1951 ;

~%

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文献:Basler Chem.Fabr. Patent: DE124407 ;

~%

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文献:Cobb American Chemical Journal, 1906 , vol. 35, p. 502

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