2,6-二甲基哌嗪, 99%,2,6-DIMETHYLPIPERAZINE
产品编号:西域试剂-WR118803| CAS NO:108-49-6| MDL NO:MFCD00005956| 分子式:C6H14N2| 分子量:114.19
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英文名称 | 2,6-DIMETHYLPIPERAZINE |
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CAS编号 | 108-49-6 |
产品熔点 | 108-111 °C(lit.) |
产品沸点 | 161.1±8.0 °C at 760 mmHg |
产品密度 | 0.8±0.1 g/cm3 |
产品闪点 | 45.0±0.0 °C |
精确质量 | 114.115700 |
PSA | 24.06000 |
LogP | -0.19 |
外观性状 | 赭色结晶粉末 |
蒸气压 | 2.3±0.3 mmHg at 25°C |
折射率 | 1.413 |
稳定性 | 避免与光、氧化物、水接触。 |
储存条件 | 储存于阴凉、通风的库房。远离火种、热源、水源。包装要求密封,不可与空气接触。应与氧化剂分开存放,切忌混储。采用防爆型照明、通风设施。禁止使用易产生火花的机械设备和工具。储区应备有泄漏应急处理设备和合适的收容材料。 |
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相关产品
符号 |
![]() ![]() GHS02, GHS07 |
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信号词 | Danger |
危害声明 | H228-H315-H319-H335 |
警示性声明 | P210-P261-P305 + P351 + P338 |
个人防护装备 | dust mask type N95 (US);Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges |
危害码 (欧洲) | F:Flammable;Xi:Irritant; |
风险声明 (欧洲) | R11;R36/37/38 |
安全声明 (欧洲) | S26-S36 |
危险品运输编码 | UN 1325 4.1/PG 2 |
WGK德国 | 3 |
包装等级 | III |
危险类别 | 4.1 |
海关编码 | 2933599090 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 11 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Highly flammable. Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. This material in sufficient quantity and reduced particle size is capable of creating a dust explosion. Flammable solid. Extinguishing Media: Use water spray to cool fire-exposed containers. Use water fog, dry chemical, carbon dioxide or alcohol type foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Remove all sources of ignition. Use a spark-proof tool. Section 7 - HANDLING and STORAGE Handling: Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Flammables-area. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 108-49-6: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Crystalline powder Color: ochre Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 162 deg C @ 760.0 Freezing/Melting Point: 106-111 deg C Autoignition Temperature: Not available. Flash Point: 44 deg C ( 111.20 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Slightly soluble. Specific Gravity/Density: Molecular Formula: C6H14N2 Molecular Weight: 114.19 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, light, ignition sources, exposure to moist air or water. Incompatibilities with Other Materials: Strong oxidizing agents, strong acids. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 108-49-6 unlisted. LD50/LC50: Not available. Carcinogenicity: 2,6-Dimethylpiperazine - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Other No information available. Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: FLAMMABLE SOLID, ORGANIC, N.O.S.* Hazard Class: 4.1 UN Number: 1325 Packing Group: II IMO Shipping Name: FLAMMABLE SOLID, ORGANIC, N.O.S. Hazard Class: 4.1 UN Number: 1325 Packing Group: II RID/ADR Shipping Name: FLAMMABLE SOLID, ORGANIC, N.O.S. Hazard Class: 4.1 UN Number: 1325 Packing group: II Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI F Risk Phrases: R 11 Highly flammable. R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 16 Keep away from sources of ignition - No smoking. S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 33 Take precautionary measures against static discharges. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 108-49-6: No information available. Canada CAS# 108-49-6 is listed on Canada's NDSL List. CAS# 108-49-6 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 108-49-6 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A |
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文献:Journal of Organic Chemistry, , vol. 45, # 24 p. 4931 - 4935 |
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文献:Journal of Organic Chemistry, , vol. 45, # 24 p. 4931 - 4935 |
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文献:Yuki Gosei Kagaku Kyokaishi, , vol. 17, p. 131,132, 135 Chem.Abstr., , p. 11392 |
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