3-溴-1-苯并呋喃, 98%,3-BROMO-1-BENZOFURAN
产品编号:西域试剂-WR124818| CAS NO:59214-70-9| 分子式:C8H5BrO| 分子量:197.03
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| 英文名称 | 3-BROMO-1-BENZOFURAN |
|---|---|
| CAS编号 | 59214-70-9 |
| 产品熔点 | 35ºC |
| 产品沸点 | 233.8±13.0 °C at 760 mmHg |
| 产品密度 | 1.6±0.1 g/cm3 |
| 产品闪点 | 95.2±19.8 °C |
| 精确质量 | 195.952377 |
| PSA | 13.14000 |
| LogP | 3.44 |
| 蒸气压 | 0.1±0.4 mmHg at 25°C |
| 折射率 | 1.639 |
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| 海关编码 | 2932999099 |
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Synonym:None know Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 20/21/22 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. Harmful if absorbed through the skin. Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. Inhalation: Harmful if inhaled. Causes respiratory tract irritation. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions. Section 7 - HANDLING and STORAGE Handling: Use with adequate ventilation. Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 59214-70-9: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: White Odor: Without to slight pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 110 deg C @20mm Hg Freezing/Melting Point: 36 - 38 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C8H5BrO Molecular Weight: 197.03 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, hydrogen bromide, bromine. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 59214-70-9 unlisted. LD50/LC50: Not available. Carcinogenicity: 3-Bromo-1-benzofuran - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: Not regulated. Hazard Class: UN Number: Packing Group: IMO Shipping Name: Not regulated. Hazard Class: UN Number: Packing Group: RID/ADR Shipping Name: Not regulated. Hazard Class: UN Number: Packing group: Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 23 Do not inhale gas/fumes/vapour/spray. S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 59214-70-9: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 59214-70-9 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 59214-70-9 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
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| 文献:Kehler, Jan; Juhl, Karsten; Norgaard, Morten Bang Patent: US2006/287386 A1, 2006 ; Location in patent: Page/Page column 17 ; |
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| 文献:Benincori, Tiziana; Brenna, Elisabetta; Sannicolo, Franco; Trimarco, Licia; Antognazza, Patrizia; et al. Journal of Organic Chemistry, 1996 , vol. 61, # 18 p. 6244 - 6251 |
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| 文献:Journal of the American Chemical Society, , vol. 105, # 19 p. 6114 - 6120 |
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| 文献:Journal of the American Chemical Society, , vol. 105, # 19 p. 6114 - 6120 |
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| 文献:Journal of the American Chemical Society, , vol. 105, # 19 p. 6114 - 6120 |
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| 文献:Journal of the American Chemical Society, , vol. 105, # 19 p. 6114 - 6120 |
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| 文献:Journal of Organic Chemistry, , vol. 61, # 18 p. 6244 - 6251 |
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