3-(二甲基氨)丙烯腈, 98%,3-(Dimethylamino)acrylonitrile
产品编号:西域试剂-WR125457| CAS NO:2407-68-3| MDL NO:MFCD00001929| 分子式:C5H8N2| 分子量:96.13
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英文名称 | 3-(Dimethylamino)acrylonitrile |
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CAS编号 | 2407-68-3 |
产品沸点 | 277.6±0.0 °C at 760 mmHg |
产品密度 | 0.9±0.1 g/cm3 |
产品闪点 | 131.9±9.1 °C |
精确质量 | 96.068748 |
PSA | 27.03000 |
LogP | 0.61 |
外观性状 | 透明黄色液体 |
蒸气压 | 0.0±0.5 mmHg at 25°C |
折射率 | 1.461 |
稳定性 | 避免氧化物,光,高温空气和水接触, |
储存条件 | 放入紧密的出藏器内,储存在阴凉,干燥的地方 |
相关文档
化学品安全说明书(MSDS)
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危害码 (欧洲) | Xn: Harmful; |
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风险声明 (欧洲) | R22 |
安全声明 (欧洲) | 26-36 |
危险品运输编码 | UN 3276 6.1/PG 2 |
包装等级 | III |
危险类别 | 6.1(b) |
海关编码 | 2926909090 |
Synonym:N,N-Dimethylaminoacrylonitrile; beta-(Dimethylamino)acrylonitrile Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 22 36/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes and skin.Light sensitive. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. May be harmful if absorbed through the skin. Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid immediately. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Fire or excessive heat may result in violent rupture of the container due to bulk polymerization. Extinguishing Media: Use foam, dry chemical, or carbon dioxide. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Avoid breathing vapor or mist. Pure vapor will be uninhibited and may polymerize in vents or other confined spaces. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from light. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels. See 29CFR 1910.1045 for regulations applying to all occupational exposures to acrylonitrile. Exposure Limits CAS# 2407-68-3: Personal Protective Equipment Eyes: Wear chemical splash goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: colorless Odor: amine-like pH: 10.1 @saturated sol. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 94 deg C @ 2.25 mm Hg Freezing/Melting Point: Not available. Autoignition Temperature: 475 deg C ( 887.00 deg F) Flash Point: 125 deg C ( 257.00 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Not available. Specific Gravity/Density: 0.88 Molecular Formula: C5H8N2 Molecular Weight: 96.13 Section 10 - STABILITY AND REACTIVITY Chemical Stability: May polymerize. Conditions to Avoid: Light, temperatures above 200C, exposure to moist air or water, confined spaces. Incompatibilities with Other Materials: Strong oxidizing agents, strong acids, strong bases. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: May occur. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 2407-68-3: UD1302500 LD50/LC50: CAS# 2407-68-3: Oral, rat: LD50 = 946 mg/kg. Carcinogenicity: 3-(Dimethylamino)acrylonitrile - Not listed by ACGIH, IARC, or NTP. Other: See actual entry in RTECS for complete information. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.* Hazard Class: 6.1 UN Number: 2810 Packing Group: III IMO Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2810 Packing Group: III RID/ADR Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2810 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 22 Harmful if swallowed. R 36/38 Irritating to eyes and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 2407-68-3: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 2407-68-3 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 2407-68-3 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
~99% ![]() 2407-68-3 |
文献:Vorbrueggen, Helmut Synlett, 2008 , # 11 p. 1603 - 1617 |
~% ![]() 2407-68-3 |
文献:Bioorganic and Medicinal Chemistry Letters, , vol. 18, # 15 p. 4388 - 4392 |
~% ![]() 2407-68-3 |
文献:Journal of Organic Chemistry, , vol. 29, p. 1800 - 1808 |
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