2-氨基-6-氯-4-羟基嘧啶, 99%,2-Amino-6-chloropyrimidin-4(3H)-one

产品编号:西域试剂-WR128374| CAS NO:1194-21-4| 分子式:C4H4ClN3O| 分子量:145.55

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西域试剂-WR128374
39.00 杭州 北京(现货)
西域试剂-WR128374
65.00 杭州 北京(现货)
西域试剂-WR128374
202.00 杭州 北京(现货)
西域试剂-WR128374
889.00 杭州 北京(现货)
西域试剂-WR128374
2328.00 杭州 北京(现货)

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英文名称2-Amino-6-chloropyrimidin-4(3H)-one
CAS编号1194-21-4
产品熔点252 °C (dec.)(lit.)
产品沸点413.7±48.0 °C at 760 mmHg
产品密度1.6±0.1 g/cm3
产品闪点204.0±29.6 °C
精确质量145.004288
PSA72.03000
LogP0.12
外观性状固体;White to Light yellow to Light orange powder to crystal
蒸气压0.0±1.0 mmHg at 25°C
折射率1.680
稳定性

如果遵照规格使用和储存则不会分解,未有已知危险反应,避免氧化物

储存条件

保持贮藏器密封、储存在阴凉、干燥的地方,确保工作间有良好的通风或排气装置

相关文档

化学品安全说明书(MSDS)

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危害码 (欧洲) Xi: Irritant;
风险声明 (欧洲) R36/37/38
安全声明 (欧洲) S26-S36
WGK德国 3
RTECS号 UW5995000
海关编码 2933599090
Name: 2-Amino-6-chloro-4-pyrimidinol hydrate 95% Material Safety Data Sheet
Synonym: 4(1H)-Pyrimidinone, 2-amino-6-chloro-, hydrate
CAS: 1194-21-4
Section 1 - Chemical Product MSDS Name:2-Amino-6-chloro-4-pyrimidinol hydrate 95% Material Safety Data Sheet
Synonym:4(1H)-Pyrimidinone, 2-amino-6-chloro-, hydrate

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
1194-21-4 2-Amino-6-chloro-4-pyrimidinol hydrate 95 unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 1194-21-4: CAS# 206658-81-3: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder
Color: light yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 252 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C4H4ClN3O.xH2O
Molecular Weight: 163.55

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 1194-21-4: UW5995000 CAS# 206658-81-3 unlisted.
LD50/LC50:
Not available.
Not available.
Carcinogenicity:
2-Amino-6-chloro-4-pyrimidinol anhydrous - Not listed by ACGIH, IARC, or NTP.
2-Amino-6-chloro-4-pyrimidinol hydrate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 1194-21-4: No information available.
CAS# 206658-81-3: No information available.
Canada
CAS# 1194-21-4 is listed on Canada's DSL List.
CAS# 1194-21-4 is not listed on Canada's Ingredient Disclosure List.
CAS# 206658-81-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1194-21-4 is not listed on the TSCA inventory.
It is for research and development use only.
CAS# 206658-81-3 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).


SECTION 16 - ADDITIONAL INFORMATION
N/A

~97%

1194-21-4结构式

1194-21-4

文献:Burgdorf, Lars T; Carell, Thomas Chemistry (Weinheim an der Bergstrasse, Germany), 2002 , vol. 8, # 1 p. 293 - 301

~99%

1194-21-4结构式

1194-21-4

文献:Hoffmann-La Roche Inc. Patent: US4939252 A1, 1990 ;

~40%

1194-21-4结构式

1194-21-4

文献:Aoyagi; Yanada; Bessho; Yoneda; Armarego Journal of Heterocyclic Chemistry, 1991 , vol. 28, # 6 p. 1537 - 1539

~%

1194-21-4结构式

1194-21-4

文献:Journal of the Chemical Society, , p. 1497,1499

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