6-碘-1,4-苯并二氧烷, ≥98%,6-Iodo-2,3-dihydro-1,4-benzodioxine

产品编号:西域试剂-WR181053| CAS NO:57744-67-9| MDL NO:MFCD00221460| 分子式:C8H7IO2| 分子量:262.04

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货号 包装 价格 库存与货期 购买量 操作
西域试剂-WR181053
190.00 杭州 北京(现货)
西域试剂-WR181053
715.00 杭州 北京(现货)

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产品名称6-碘-1,4-苯并二氧烷, ≥98%
英文名称6-Iodo-2,3-dihydro-1,4-benzodioxine
CAS编号57744-67-9
产品沸点98 °C
产品密度1.866g/cm3
产品闪点100-102°C/0.25mm
精确质量261.94900
PSA18.46000
LogP2.06240
折射率1.629
稳定性

如果遵照规格使用和储存则不会分解,未有已知危险反应

储存条件

保持贮藏器密封、储存在阴凉、干燥的地方,确保工作间有良好的通风或排气装置

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危害码 (欧洲) C
风险声明 (欧洲) R34:Causes burns.
安全声明 (欧洲) S45-S36/37/39-S26
危险品运输编码 1760
包装等级 II
危险类别 8
海关编码 2932999099
Name: 6-Iodo-2 3-dihydro-1 4-benzodioxine 97% Material Safety Data Sheet
Synonym: 3,4-Ethylenedioxyiodobenzen
CAS: 57744-67-9
Section 1 - Chemical Product MSDS Name:6-Iodo-2 3-dihydro-1 4-benzodioxine 97% Material Safety Data Sheet
Synonym:3,4-Ethylenedioxyiodobenzen

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
57744-67-9 6-Iodo-2,3-dihydro-1,4-benzodioxine 97% unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 57744-67-9: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: light purple
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 100 - 102 deg C @0.2mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C8H7IO2
Molecular Weight: 262

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Acids, bases, oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen iodide, iodine.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 57744-67-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
6-Iodo-2,3-dihydro-1,4-benzodioxine - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 57744-67-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 57744-67-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 57744-67-9 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

~85%

57744-67-9结构式

57744-67-9

文献:SLOAN-KETTERING INSTITUTE FOR CANCER RESEARCH; CHIOSIS, Gabriela; TALDONE, Tony; SUN, Weilin Patent: WO2011/44394 A1, 2011 ; Location in patent: Page/Page column 110 ;

~75%

57744-67-9结构式

57744-67-9

文献:Sosnowski, Maciej; Skulski, Lech Molecules, 2005 , vol. 10, # 2 p. 401 - 406

~11%

57744-67-9结构式

57744-67-9

文献:Tetrahedron Letters, , vol. 37, # 14 p. 2441 - 2444

~12%

57744-67-9结构式

57744-67-9

文献:Journal of the Chemical Society - Perkin Transactions 1, , # 5 p. 787 - 793

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