2',4',5'-三氟苯乙酮, 99.9%,2',4',5'-Trifluoroacetophenone
产品编号:西域试剂-WR185890| CAS NO:129322-83-4| MDL NO:MFCD00061193| 分子式:F3C6H2COCH3| 分子量:174.12
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产品名称 | 2',4',5'-三氟苯乙酮, 99.9% |
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英文名称 | 2',4',5'-Trifluoroacetophenone |
CAS编号 | 129322-83-4 |
产品熔点 | -7 |
产品沸点 | 199.8±35.0 °C at 760 mmHg |
产品密度 | 1.3±0.1 g/cm3 |
产品闪点 | 71.1±0.0 °C |
精确质量 | 174.029251 |
PSA | 17.07000 |
LogP | 1.47 |
外观性状 | 透明黄色液体 |
蒸气压 | 0.3±0.4 mmHg at 25°C |
折射率 | 1.455 |
稳定性 | 如果遵照规格使用和储存则不会分解,未有已知危险反应 避免氧化物 |
储存条件 | 保持贮藏器密封、储存在阴凉、干燥的地方,确保工作间有良好的通风或排气装置 |
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符号 |
![]() GHS07 |
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信号词 | Warning |
危害声明 | H315-H319-H335 |
警示性声明 | P261-P305 + P351 + P338 |
个人防护装备 | Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
危害码 (欧洲) | Xi:Irritant; |
风险声明 (欧洲) | R36/37/38 |
安全声明 (欧洲) | S26-S36/37/39 |
危险品运输编码 | NONH for all modes of transport |
WGK德国 | 3 |
海关编码 | 2914700090 |
Synonym:1-(2,4,5-Trifluorphenyl)-ethanon Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 22 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Harmful if swallowed.The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: May cause irritation of the digestive tract. Inhalation: May cause respiratory tract irritation. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Use with adequate ventilation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 129322-83-4: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: clear yellow Odor: Aromatic odor pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 76 - 79 deg C @ 760.00mm Hg Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: > 100 deg C (> 212.00 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: 0.5 G/L WATER(20C) Specific Gravity/Density: 1.3800g/cm3 Molecular Formula: C8H5F3O Molecular Weight: 174.12 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stability unknown. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents, strong bases. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, hydrogen fluoride gas. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 129322-83-4 unlisted. LD50/LC50: Not available. Carcinogenicity: 2,4,5-Trifluoroacetophenone - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 22 Harmful if swallowed. Safety Phrases: WGK (Water Danger/Protection) CAS# 129322-83-4: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 129322-83-4 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 129322-83-4 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
~88% ![]() 129322-83-4 |
文献:Braish, Tamim F.; Fox, Darrell E. Organic Preparations and Procedures International, 1991 , vol. 23, # 5 p. 655 - 658 |
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