2,6-二氟二苯甲酮, 99%,2,6-Difluorobenzophenone
产品编号:西域试剂-WR186039| CAS NO:59189-51-4| MDL NO:MFCD00009895| 分子式:C13H8F2O| 分子量:218.2
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产品名称 | 2,6-二氟二苯甲酮, 99% |
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英文名称 | 2,6-Difluorobenzophenone |
CAS编号 | 59189-51-4 |
产品沸点 | 120 °C (2 mmHg) |
产品密度 | 1.244 g/mL at 25 °C(lit.) |
产品闪点 | >230 °F |
精确质量 | 218.05400 |
PSA | 17.07000 |
LogP | 3.19580 |
折射率 | n20/D 1.5645(lit.) |
稳定性 | 避免接触氧化物 |
储存条件 | 在密封的贮藏器内,并放置阴凉,干燥的地方通风保存 |
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危害码 (欧洲) | Xi |
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风险声明 (欧洲) | 36/37/38 |
安全声明 (欧洲) | S26-S37/39 |
WGK德国 | 3 |
海关编码 | 2914700090 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 59189-51-4: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Clear liquid Color: colorless Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 120 deg C @2mmHg Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: > 110 deg C (> 230.00 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: 1.244 Molecular Formula: C13H8F2O Molecular Weight: 218.2 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, hydrogen fluoride gas. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 59189-51-4 unlisted. LD50/LC50: Not available. Carcinogenicity: 2,6-Difluorobenzophenone - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 59189-51-4: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 59189-51-4 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 59189-51-4 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
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文献:Dong, Zhibing; Clososki, Giuliano C.; Wunderlich, Stefan H.; Unsinn, Andreas; Li, Jinshan; Knochel, Paul Chemistry - A European Journal, 2009 , vol. 15, # 2 p. 457 - 468 |
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文献:Journal of Organic Chemistry, , vol. 78, # 4 p. 1665 - 1669 |
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文献:Zhao, Baowei; Lu, Xiyan Tetrahedron Letters, 2006 , vol. 47, # 38 p. 6765 - 6768 |