异腈甲基磷酸二乙酯, 98%,DIETHYL ISOCYANOMETHYLPHOSPHONATE
产品编号:西域试剂-WR192499| CAS NO:41003-94-5| MDL NO:MFCD00042951| 分子式:C6H12NO3P| 分子量:177.14
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英文名称 | DIETHYL ISOCYANOMETHYLPHOSPHONATE |
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CAS编号 | 41003-94-5 |
产品沸点 | 84-87ºC0.1 mm Hg(lit.) |
产品密度 | 1.105 g/mL at 25ºC(lit.) |
产品闪点 | >230 °F |
精确质量 | 177.05500 |
PSA | 45.34000 |
LogP | 1.36000 |
外观性状 | Liquid | Clear colorless to yellow |
折射率 | n20/D 1.433(lit.) |
稳定性 | 遵照规定使用和储存则不会分解。 |
储存条件 | 密闭于阴凉干燥环境中 |
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符号 |
![]() GHS07 |
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信号词 | Warning |
危害声明 | H302 + H312 + H332-H315-H319-H335 |
警示性声明 | P261-P280-P305 + P351 + P338 |
个人防护装备 | Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
危害码 (欧洲) | Xi |
风险声明 (欧洲) | R36/37/38 |
安全声明 (欧洲) | S26-S37/39 |
危险品运输编码 | NONH for all modes of transport |
WGK德国 | 3 |
海关编码 | 2931900090 |
Synonym:Isocyanomethylphosphononic acid diethyleste Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Light sensitive. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Keep refrigerated. (Store below 4C/39F.) Store in a tightly closed container. Store in a dry area. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 41003-94-5: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: colorless to light yellow Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 84 - 87 deg C @0.1mmHg Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: > 110 deg C (> 230.00 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: 1.105 Molecular Formula: C6H12NO3P Molecular Weight: 177.14 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, light. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Nitrogen oxides, phosphine, carbon monoxide, oxides of phosphorus, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 41003-94-5 unlisted. LD50/LC50: Not available. Carcinogenicity: Diethyl isocyanomethylphosphonate - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Other No information available. Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37 Wear suitable protective clothing and gloves. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 41003-94-5: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 41003-94-5 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 41003-94-5 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
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文献:Schoellkopf,U. et al. Justus Liebigs Annalen der Chemie, 1974 , p. 44 - 53 |
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