甲磺酸异丙酯,Isopropyl methanesulfonate,98%

产品编号:西域试剂-WR192842| CAS NO:926-06-7| 分子式:C4H10O3S| 分子量:138.19

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货号 包装 价格 库存与货期 购买量 操作
西域试剂-WR192842
90.00 杭州 北京(现货)
西域试剂-WR192842
162.00 杭州 北京(现货)
西域试剂-WR192842
230.00 杭州 北京(现货)
西域试剂-WR192842
477.00 杭州 北京(现货)
西域试剂-WR192842
1822.00 杭州 北京(现货)

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产品名称甲磺酸异丙酯
英文名称Isopropyl methanesulfonate
CAS编号926-06-7
产品熔点7°C(lit.)
产品沸点220.0±9.0 °C at 760 mmHg
产品密度1.1±0.1 g/cm3
产品闪点86.9±18.7 °C
精确质量138.035065
PSA51.75000
LogP0.31
外观性状透明无色液体
蒸气压0.2±0.4 mmHg at 25°C
折射率1.422
稳定性避免与不相容材料接触。 与强氧化剂反应。
储存条件

密封储存,储存于阴凉、干燥的库房。远离腐蚀区。冷藏温度为4 ºC。

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危害码 (欧洲) C: Corrosive;
风险声明 (欧洲) R68
安全声明 (欧洲) S26;S45;S36/S37/S39
危险品运输编码 UN 3265 8 / PGII
RTECS号 PB2275000
包装等级 III
海关编码 2905199090
Name: Isopropyl Methanesulfonate Material Safety Data Sheet
Synonym: Methanesulfonic Acid, 1-Methylethyl Ester
CAS: 926-06-7
Section 1 - Chemical Product MSDS Name:Isopropyl Methanesulfonate Material Safety Data Sheet
Synonym:Methanesulfonic Acid, 1-Methylethyl Ester

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
926-06-7 Isopropyl Methane Sulphonate ca 100 213-132-0
Hazard Symbols: C
Risk Phrases: 34 40

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Causes burns. Limited evidence of a carcinogenic effect.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary edema. May cause systemic effects.
Chronic:
Effects may be delayed.

Section 4 - FIRST AID MEASURES
Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Cool containers with flooding quantities of water until well after fire is out.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Discard contaminated shoes.
Storage:
Store in a cool, dry place. Keep container closed when not in use.
Corrosives area. Keep refrigerated. (Store below 4C/39F.)

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 926-06-7: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 82 deg C @ 6.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 104 deg C ( 219.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C4H10O3S
Molecular Weight: 138.19

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 926-06-7: PB2275000 LD50/LC50:
Not available.
Carcinogenicity:
Isopropyl Methane Sulphonate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3261
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing group: III

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
R 40 Limited evidence of a carcinogenic effect.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 926-06-7: No information available.
Canada
CAS# 926-06-7 is listed on Canada's NDSL List.
CAS# 926-06-7 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 926-06-7 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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文献:Willemsen, Jorgen S.; Van Hest, Jan C.M.; Rutjes, Floris P.J.T. Beilstein Journal of Organic Chemistry, 2013 , vol. 9, p. 960 - 965

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文献:Devekki, A. V.; Koshelev, Yu. V.; Malov, Yu. I. Journal of Organic Chemistry USSR (English Translation), 1983 , vol. 19, p. 829 - 834 Zhurnal Organicheskoi Khimii, 1983 , vol. 19, # 5 p. 935 - 941

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文献:Industrial and Engineering Chemistry, , vol. 40, p. 1129

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文献:Canadian Journal of Chemistry, , vol. 35, p. 1319,1322

~0%

详细
文献:Phosphorus and Sulfur and the Related Elements, , vol. 18, p. 209 - 212

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