1-(4-甲氧基苯基)环己烷甲腈, 99%,1-(4-Methoxyphenyl)cyclohexanecarbonitrile

产品编号:西域试剂-WR196636| CAS NO:36263-51-1| MDL NO:MFCD00021282| 分子式:C14H17NO| 分子量:215.29

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货号 包装 价格 库存与货期 购买量 操作
西域试剂-WR196636
74.00 杭州 北京(现货)
西域试剂-WR196636
257.00 杭州 北京(现货)
西域试剂-WR196636
899.00 杭州 北京(现货)

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英文名称1-(4-Methoxyphenyl)cyclohexanecarbonitrile
CAS编号36263-51-1
产品熔点40-45ºC
产品沸点176-179ºC (2 torr)
产品密度1.0778
产品闪点152.6ºC
精确质量215.13100
PSA33.02000
LogP3.42068
外观性状无色至黄色-棕色低熔点固体
折射率1.538
稳定性

常规情况下不会分解,没有危险反应

储存条件

密封、阴凉、干燥、通风保存

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危害码 (欧洲) Xn:Harmful;
风险声明 (欧洲) R20/21/22
安全声明 (欧洲) S24/25
危险品运输编码 UN 3276
包装等级 III
危险类别 6.1
海关编码 2926909090
Name: 1-(4-Methoxyphenyl)-1-Cyclohexane-Carbonitrile 95% Material Safety Data Sheet
Synonym:
CAS: 36263-51-1
Section 1 - Chemical Product MSDS Name:1-(4-Methoxyphenyl)-1-Cyclohexane-Carbonitrile 95% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
36263-51-1 1-(4-Methoxyphenyl)-1-Cyclohexanecarbo 95 252-938-7
Hazard Symbols: XN
Risk Phrases: 20/21/22

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation. The toxicological properties of this material have not been fully investigated.
Skin:
May cause skin irritation. The toxicological properties of this material have not been fully investigated.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 36263-51-1: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 44.00 - 46.00 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C14H17NO
Molecular Weight: 215.29

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 36263-51-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-(4-Methoxyphenyl)-1-Cyclohexanecarbonitrile - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 36263-51-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 36263-51-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 36263-51-1 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

~61%

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文献:TOPOTARGET UK LIMITED Patent: WO2004/65354 A1, 2004 ; Location in patent: Page 103; 114; 71; 75 ;

~90%

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文献:Duez, Stephanie; Bernhardt, Sebastian; Heppekausen, Johannes; Fleming, Fraser F.; Knochel, Paul Organic Letters, 2011 , vol. 13, # 7 p. 1690 - 1693

~78%

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文献:Wu, Lingyun; Hartwig, John F. Journal of the American Chemical Society, 2005 , vol. 127, # 45 p. 15824 - 15832

~93%

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文献:Chen, Gang; Wang, Zheng; Wu, Jiang; Ding, Kuiling Organic Letters, 2008 , vol. 10, # 20 p. 4573 - 4576

~92%

36263-51-1结构式

36263-51-1

文献:Yanagisawa, Arata; Nezu, Tetsuya; Mohri, Shin-Ichiro Organic Letters, 2009 , vol. 11, # 22 p. 5286 - 5289

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