1-溴-2,4,6-三氟苯, 99%,1-Bromo-2,4,6-trifluorobenzene

产品编号:西域试剂-WR196906| CAS NO:2367-76-2| MDL NO:MFCD00000334| 分子式:BrC6H2F3| 分子量:210.98

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货号 包装 价格 库存与货期 购买量 操作
西域试剂-WR196906
76.00 杭州 北京(现货)
西域试剂-WR196906
257.00 杭州 北京(现货)

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产品名称1-溴-2,4,6-三氟苯, 99%
英文名称1-Bromo-2,4,6-trifluorobenzene
CAS编号2367-76-2
产品熔点3.5 °C(lit.)
产品沸点135.8±35.0 °C at 760 mmHg
产品密度1.8±0.1 g/cm3
产品闪点32.1±21.8 °C
精确质量209.929184
LogP3.02
外观性状无色液体
蒸气压9.4±0.2 mmHg at 25°C
折射率1.486
稳定性

避免氧化物接触

储存条件

保持容器密封,放入紧密的出藏器内,储存在阴凉,干燥的地方

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符号 GHS02 GHS07
GHS02, GHS07
信号词 Warning
危害声明 H226-H315-H319-H335
警示性声明 P261-P305 + P351 + P338
个人防护装备 Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
危害码 (欧洲) Xi:Irritant;
风险声明 (欧洲) R10;R36/37/38
安全声明 (欧洲) S26-S37/39-S16
危险品运输编码 UN 1993 3/PG 3
WGK德国 3
包装等级 III
危险类别 3
海关编码 2903999090
Name: 1-Bromo-2 4 6-trifluorobenzene 99% Material Safety Data Sheet
Synonym: None
CAS: 2367-76-2
Section 1 - Chemical Product MSDS Name:1-Bromo-2 4 6-trifluorobenzene 99% Material Safety Data Sheet
Synonym:None

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
2367-76-2 1-Bromo-2,4,6-trifluorobenzene 99.0 219-125-9
Hazard Symbols: XI
Risk Phrases: 10 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Flammable. Irritating to eyes, respiratory system and skin.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Vapors may cause dizziness or suffocation.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Antidote: None reported.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Flammables-area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 2367-76-2: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 140.5 deg C
Freezing/Melting Point: 3.5 deg C
Autoignition Temperature: Not available.
Flash Point: 137 deg F ( 58.33 deg C)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.7900g/cm3
Molecular Formula: C6H2BrF3
Molecular Weight: 210.99

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stability unknown.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 2367-76-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-Bromo-2,4,6-trifluorobenzene - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing Group: III
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing Group: III
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: III

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 10 Flammable.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 33 Take precautionary measures against static
discharges.
S 37 Wear suitable gloves.
S 37/39 Wear suitable gloves and eye/face
protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 2367-76-2: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 2367-76-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 2367-76-2 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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文献:BASF SE Patent: US2010/56820 A1, 2010 ; Location in patent: Page/Page column 4 ;

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文献:Journal of the American Chemical Society, , vol. 73, p. 153 Journal of the American Chemical Society, , vol. 81, p. 94,98

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2367-76-2结构式

2367-76-2

文献:Journal of the American Chemical Society, , vol. 73, p. 153 Journal of the American Chemical Society, , vol. 81, p. 94,98

~%

2367-76-2结构式

2367-76-2

文献:Journal of the American Chemical Society, , vol. 73, p. 153 Journal of the American Chemical Society, , vol. 81, p. 94,98

~%

2367-76-2结构式

2367-76-2

文献:Journal of the American Chemical Society, , vol. 73, p. 153 Journal of the American Chemical Society, , vol. 81, p. 94,98

~%

2367-76-2结构式

2367-76-2

文献:Journal of the American Chemical Society, , vol. 73, p. 153 Journal of the American Chemical Society, , vol. 81, p. 94,98

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