1-硝基-4-(三氟甲氧基)苯, 98%,1-Nitro-4-(trifluoromethoxy)benzene
产品编号:西域试剂-WR197064| CAS NO:713-65-5| MDL NO:MFCD00040302| 分子式:C7H4F3NO3| 分子量:207.11
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产品名称 | 1-硝基-4-(三氟甲氧基)苯, 98% |
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英文名称 | 1-Nitro-4-(trifluoromethoxy)benzene |
CAS编号 | 713-65-5 |
产品熔点 | 15°C |
产品沸点 | 217.4±35.0 °C at 760 mmHg |
产品密度 | 1.5±0.1 g/cm3 |
产品闪点 | 85.3±25.9 °C |
精确质量 | 207.014328 |
PSA | 55.05000 |
LogP | 3.07 |
蒸气压 | 0.2±0.4 mmHg at 25°C |
折射率 | 1.476 |
稳定性 | 远离氧化物,高温,明火。 |
储存条件 | 存放在密封容器内,并放在阴凉,干燥处。储存的地方必须远离氧化剂。 |
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危害码 (欧洲) | Xi:Irritant; |
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风险声明 (欧洲) | R36/37/38 |
安全声明 (欧洲) | S26-S36 |
海关编码 | 2909309090 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 713-65-5: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: colorless - pale yellow Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 87 - 89 deg C @15mmHg Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C7H4F3NO3 Molecular Weight: 207 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Oxidizing agents, reducing agents, acids, bases. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide, fluorine, hydrogen fluoride gas. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 713-65-5 unlisted. LD50/LC50: Not available. Carcinogenicity: 1-Nitro-4-(trifluoromethoxy)benzene - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 713-65-5: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 713-65-5 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 713-65-5 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
~91% ![]() 713-65-5 |
文献:Al-Masum, Mohammad; Welch, Rebecca L. Tetrahedron Letters, 2014 , vol. 55, # 10 p. 1726 - 1728 |
~87% ![]() 713-65-5 |
文献:Journal of the American Chemical Society, , vol. 109, p. 3708 |
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