5-氯-2-甲氧基苯磺酰氯, 99%,5-Chloro-2-methoxybenzenesulfonyl chloride

产品编号:西域试剂-WR202345| CAS NO:22952-32-5| MDL NO:MFCD00052959| 分子式:C7H6Cl2O3S| 分子量:241.1

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西域试剂-WR202345
72.00 杭州 北京(现货)
西域试剂-WR202345
214.00 杭州 北京(现货)
西域试剂-WR202345
858.00 杭州 北京(现货)
西域试剂-WR202345
2444.00 杭州 北京(现货)

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英文名称5-Chloro-2-methoxybenzenesulfonyl chloride
CAS编号22952-32-5
产品熔点100-104 °C
产品沸点344.6±32.0 °C at 760 mmHg
产品密度1.5±0.1 g/cm3
产品闪点162.2±25.1 °C
精确质量239.941467
PSA51.75000
LogP2.96
外观性状白色结晶粉末
蒸气压0.0±0.7 mmHg at 25°C
折射率1.550
稳定性

如果遵照规格使用和储存则不会分解

避免接触氧化物,水分/潮湿,碱

储存条件

保持贮藏器密封

放入紧密的贮藏器内,储存在阴凉,干燥的地方

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危害码 (欧洲) C:Corrosive;
风险声明 (欧洲) R34
安全声明 (欧洲) S8-S45-S36/37/39-S26
危险品运输编码 3261
包装等级 II
危险类别 8
海关编码 2909309090
Name: 5-Chloro-2-methoxybenzenesulfonyl chloride Material Safety Data Sheet
Synonym: None
CAS: 22952-32-5
Section 1 - Chemical Product MSDS Name:5-Chloro-2-methoxybenzenesulfonyl chloride Material Safety Data Sheet
Synonym:None

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
22952-32-5 5-Chloro-2-methoxybenzenesulfonyl chlo 100 unlisted
Hazard Symbols: C
Risk Phrases: 34

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Causes burns.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary edema. May cause systemic effects.
Chronic:
Effects may be delayed.

Section 4 - FIRST AID MEASURES
Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam. Do NOT get water inside containers.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation. Do not get water inside containers.

Section 7 - HANDLING and STORAGE
Handling:
Minimize dust generation and accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing.
Keep container tightly closed. Do not ingest or inhale. Do not allow contact with water. Use only in a chemical fume hood. Discard contaminated shoes. Keep from contact with moist air and steam.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Corrosives area. Store protected from moisture.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 22952-32-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 101 -103 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C7H6Cl2O3S
Molecular Weight: 241.0062

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not currently available.
Conditions to Avoid:
Dust generation, exposure to moist air or water.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, oxides of sulfur, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 22952-32-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
5-Chloro-2-methoxybenzenesulfonyl chloride - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Fish: Pseudomonas putida:

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: CORROSIVE SOLID, N.O.S.*
Hazard Class: 8
UN Number: 1759
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing group: III

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 22952-32-5: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 22952-32-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 22952-32-5 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

~76%

22952-32-5结构式

22952-32-5

文献:Guo, Cheng; Qiu, Jun; Zhang, Xumu; Verdugo, Dawn; Larter, Martin L.; Christie, Ray; Kenney, Patrick; Walsh, Patrick J. Tetrahedron, 1997 , vol. 53, # 12 p. 4145 - 4158

~%

22952-32-5结构式

22952-32-5

文献:Tetrahedron, , vol. 53, # 12 p. 4145 - 4158

~%

22952-32-5结构式

22952-32-5

文献:Journal of the Chemical Society, , vol. 127, p. 2746

~%

22952-32-5结构式

22952-32-5

文献:Journal of the Chemical Society, , vol. 127, p. 2746

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