三氟醋酸汞 ,Mercuric trifluoroacetate ,99%

产品编号:Bellancom-B397843| CAS NO:13257-51-7| 分子式:C2HF3HgO2| 分子量:314.6133

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货号 包装 价格 库存与货期 购买量 操作
Bellancom-B397843
3956.00 杭州 北京(现货)
Bellancom-B397843
1388.00 杭州 北京(现货)

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产品名称 三氟醋酸汞
英文名称Mercuric trifluoroacetate
CAS编号13257-51-7
产品熔点171-173ºC
产品沸点72.2ºC at 760mmHg
精确质量427.94100
PSA52.60000
LogP1.10990
外观性状近乎于白色至淡米色结晶粉末
蒸气压96.2mmHg at 25°C
溶解性soluble
稳定性

1.常温常压下稳定

避免的物料 水分/潮湿空气。易溶于二甲基甲酰胺(DMF),二甲亚砜(DMSO)、丙酮、乙酸乙酯、四氢呋喃、乙醚、苯和二氯甲烷等有机溶剂中,可发生选择性羟汞化(oxymercuration)等反应。熔点为166~167℃的无水三氟乙酸汞,可保存在用固体氢氧化钾作干燥剂的干燥器中达9个月之久。若含水,其熔点可降至100℃。
储存条件

常温密闭,阴凉通风干燥

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符号 GHS06 GHS08 GHS09
GHS06, GHS08, GHS09
信号词 Danger
危害声明 H300 + H310 + H330-H373-H410
警示性声明 Missing Phrase - N15.00950417-P260-P262-P280-P302 + P352 + P310-P304 + P340 + P310
个人防护装备 Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
危害码 (欧洲) T+:Verytoxic;N:Dangerous for the environment;
风险声明 (欧洲) R26/27/28;R33;R50/53
安全声明 (欧洲) S13-S28-S36-S45-S60-S61
危险品运输编码 UN 2025
WGK德国 3
包装等级 II
危险类别 6.1
海关编码 29159080
Name: Mercuric trifluoroacetate 98% Material Safety Data Sheet
Synonym: Trifluoroacetic acid, mercury(II) sal
CAS: 13257-51-7
Section 1 - Chemical Product MSDS Name:Mercuric trifluoroacetate 98% Material Safety Data Sheet
Synonym:Trifluoroacetic acid, mercury(II) sal

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
13257-51-7 Mercuric trifluoroacetate, 98% 98% 236-250-4
Hazard Symbols: T+
Risk Phrases: 26/27/28 33

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Very toxic by inhalation, in contact with skin and if swallowed.
Danger of cumulative effects.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause liver and kidney damage. May cause perforation of the digestive tract. May cause vascular collapse and damage. Causes severe pain, nausea, vomiting, diarrhea, and shock. May cause central nervous system effects.
Inhalation:
Causes respiratory tract irritation. May cause effects similar to those described for ingestion.
Chronic:
Prolonged or repeated inhalation of dusts may cause neurological damage. May cause liver and kidney damage. May cause reproductive and fetal effects. May cause tremors, irritability, loss of memory and intellect. May also cause Pink disease characterized by skin, cardiovascular, and neurobehavioral abnormalities.

Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
SPEED IS ESSENTIAL. A DOCTOR MUST BE NOTIFIED AT ONCE. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, or carbon dioxide.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. Do not allow contact with water. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Poison room locked.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits CAS# 13257-51-7: United States OSHA: 0.1 mg/m3 Ceiling (listed under Mercury, ary and inorganic compounds).
Belgium - TWA: (listed as mercury, aryl and inorganic compounds): mg/m3 VLE (as Hg) France - VME: (listed as mercury, aryl and inorganic compounds): mg/m3 VME (as Hg) Germany: (listed as mercury, aryl and inorganic compounds): 0.1 m VME (as Hg) Malaysia: (listed as mercury, aryl and inorganic compounds): 0.1 mg/m3 TWA (as Hg) Spain: (listed as mercury, aryl and inorganic compounds): 0.1 mg/ VLA-ED (as Hg) Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: slightly yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: @ 760.00mm Hg
Freezing/Melting Point: 171 - 173 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C4F6O4Hg
Molecular Weight: 426.61

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
None reported.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen fluoride gas, mercury/mercury oxides.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 13257-51-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Mercuric trifluoroacetate, 98% - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: MERCURY COMPOUND, SOLID, N.O.S.
Hazard Class: 6.1
UN Number: 2025
Packing Group: II
IMO
Shipping Name: MERCURY COMPOUND, SOLID, N.O.S.
Hazard Class: 6.1
UN Number: 2025
Packing Group: II
RID/ADR
Shipping Name: MERCURY COMPOUND, SOLID, N.O.S.
Hazard Class: 6.1
UN Number: 2025
Packing group: II

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+
Risk Phrases:
R 26/27/28 Very toxic by inhalation, in contact with
skin and if swallowed.
R 33 Danger of cumulative effects.
Safety Phrases:
S 13 Keep away from food, drink and animal feeding
stuffs.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36 Wear suitable protective clothing.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 13257-51-7: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 13257-51-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 13257-51-7 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A
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