5-甲酰基-2-甲基-3-糠酸甲酯 ,Methyl 5-formyl-2-methyl-3-furoate
产品编号:Bellancom-B405900| CAS NO:81661-26-9| 分子式:C8H8O4| 分子量:168.14700
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产品名称 | 5-甲酰基-2-甲基-3-糠酸甲酯 |
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英文名称 | Methyl 5-formyl-2-methyl-3-furoate |
CAS编号 | 81661-26-9 |
产品熔点 | 83ºC |
产品沸点 | 275.2ºC at 760 mmHg |
产品密度 | 1.217g/cm3 |
产品闪点 | 120.2ºC |
精确质量 | 168.04200 |
PSA | 56.51000 |
LogP | 1.18710 |
折射率 | 1.518 |
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风险声明 (欧洲) | 36/37/38 |
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安全声明 (欧洲) | S24/25 |
海关编码 | 2932190090 |
Synonym:5-Formyl-2-methyl-furan-3-carboxylic acid methyl este Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Light sensitive. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: May cause respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Do not store in direct sunlight. Store in a tightly closed container. Store under nitrogen. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 81661-26-9: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: yellow Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 82.5 - 83.5 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C8H8O4 Molecular Weight: 168.15 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials, light. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 81661-26-9 unlisted. LD50/LC50: Not available. Carcinogenicity: Methyl 5-formyl-2-methyl-3-furoate - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 81661-26-9: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 81661-26-9 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 81661-26-9 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
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文献:Stephen; Hashmi; Woelfle; Ata, Filiz; Hamzic, Melissa; Salathe, Ralph; Frey, Wolfgang Advanced Synthesis and Catalysis, 2006 , vol. 348, # 16-17 p. 2501 - 2508 |
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文献:EVOTEC NEUROSCIENCES GMBH; MADDEN, James; HALLETT, David James; PARKES, Alastair; RAOOF, Ali; WANG, Xialou Patent: WO2010/20556 A1, 2010 ; Location in patent: Page/Page column 126-127 ; WO 2010/020556 A1 |
~41% ![]() 81661-26-9 |
文献:Ballesteros, Juan Sanchez; McPhee, Derek James; Hernandez, Dolores Hernandez Bulletin de la Societe Chimique de France, 1982 , vol. 2, # 5-6 p. 176 - 180 |
~71% ![]() 81661-26-9 |
文献:Pevzner Russian Journal of General Chemistry, 2001 , vol. 71, # 7 p. 1045 - 1049 |
~% ![]() 81661-26-9 |
文献:Bulletin de la Societe Chimique de France, , vol. 2, # 5-6 p. 176 - 180 |
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