甲醇铜(II) ,COPPER(II) METHOXIDE 97 ,99.9%

产品编号:Bellancom-B14006| CAS NO:1184-54-9| 分子式:Cu(OCH3)2| 分子量:125.61

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货号 包装 价格 库存与货期 购买量 操作
Bellancom-B14006
3913.00 杭州 北京(现货)
Bellancom-B14006
825.00 杭州 北京(现货)

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产品名称 甲醇铜(II)
英文名称COPPER(II) METHOXIDE 97
CAS编号1184-54-9
产品熔点206ºC (dec.)(lit.)
精确质量126.98200
PSA40.46000
外观性状Powder | Green
溶解性Reacts with water.
稳定性

常温常压下稳定

储存条件

常温 ,阴凉,避光,通风干燥处

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化学品安全说明书(MSDS)

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符号 GHS07
GHS07
信号词 Warning
危害声明 H315-H319-H335
警示性声明 P261-P305 + P351 + P338
个人防护装备 dust mask type N95 (US);Eyeshields;Gloves
危害码 (欧洲) Xi
风险声明 (欧洲) R36/37/38
安全声明 (欧洲) S26
危险品运输编码 UN3180
WGK德国 3
包装等级 II
危险类别 4.1

Section 1: Product Identification
Chemical Name:Copper(II) methoxide, 99%
CAS Registry Number:1184-54-9
Formula:Cu(OCH3)2
EINECS Number:none
Chemical Family:metal alkoxide
Synonym:Cupric methylate

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound1184-54-9100%no datano data

Section 3: Hazards Identification
Irritating to skin, eyes and respiratory tract. Moisture will produce methanol vapor which may cause blindness,
Emergency Overview:
intoxication, dizziness and coma.
Primary Routes of Exposure:Ingestion, inhalation, contact with skin and eyes.
Eye Contact:Causes severe irritation to the eyes. Delayed blindness may occur through atrophy of the optic nerve.
Skin Contact:Dehydrating agent. Liquid causes slight to mild irritation of the skin.
Inhalation:Methanol vapor is irritating to the respiratory tract and may cause headache, dizziness, coma and blindness.
Ingestion:Ingestion may cause nausea, vomiting, headache, coma and death.
Irritating to skin, eyes and respiratory tract. Methanol vapors may cause blurred vision, blindness, intoxication,
Acute Health Affects:
dizziness, headache, nausea, coma and death.
Rapid hydrolysis on human contact produces methanol which may cause atrophy of the optic nerve producing
Chronic Health Affects:blindness. The dust of copper compounds may cause metal fume fever, hemolysis of the red blood cells and
injury to the liver, lungs, kidneys and pancreas.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:no data
Explosion Limits:no data
Extinguishing Medium:carbon dioxide, dry powder or foam
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire, this material may emit toxic organic fumes and copper oxide dust.
Decomposion Products:
Unusual Fire or Explosion Hazards: exposure to moisture may produce flammable methanol

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Avoid contact with water. Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
Store the material cold, in a tightly sealed container. Handle the material in a ventilated area. If container is left
Handling and Storage:
open product may absorb moisture and carbon dioxide from atmosphere and release methanol vapor.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:Handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:blue powder
Molecular Weight:125.61
Melting Point:no data
Boiling Point:no data
Vapor Pressure:not applicable
Specific Gravity:no data
Odor:alcohol-like odor
Solubility in Water:decomposes in water

SECTION 10: Stability and Reactivity
Stability:moisture sensitive (store cold)
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:keep away from moisture
Incompatibility:oxidizing agents, active metals and chlorine
Decomposition Products:carbon dioxide, carbon monoxide, organic fumes and copper salts.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory
SARA (Title 313):See category code N100 for reporting.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

~83%

1184-54-9结构式

1184-54-9

文献:Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 921 - 926

~0%

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1184-54-9

文献:Inorganic Chemistry, , vol. 31, p. 4503 - 4509

~%

1184-54-9结构式

1184-54-9

文献:Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, , vol. 16, p. 1217 - 1224

~%

1184-54-9结构式

1184-54-9

文献:Zeitschrift fuer Anorganische und Allgemeine Chemie, , vol. 581, p. 48 - 50

~%

1184-54-9结构式

1184-54-9

文献:Polyhedron, , vol. 21, # 20 p. 2017 - 2020

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