三(2,2,6,6-四甲基-3,5-庚二酮酸)钐(III) [Sm(TMHD)3] ,Samarium(III)2,2,6,6-tetramethylheptane-dionate ,99.9%(REO)

产品编号:Bellancom-B413802| CAS NO:15492-50-9| 分子式:C33H60O6Sm| 分子量:703.1859

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货号 包装 价格 库存与货期 购买量 操作
Bellancom-B413802
3096.00 杭州 北京(现货)
Bellancom-B413802
10840.00 杭州 北京(现货)
Bellancom-B413802
1124.00 杭州 北京(现货)
Bellancom-B413802
561.00 杭州 北京(现货)
Bellancom-B413802
1969.00 杭州 北京(现货)

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产品名称 三(2,2,6,6-四甲基-3,5-庚二酮酸)钐(III) [Sm(TMHD)3]
英文名称Samarium(III)2,2,6,6-tetramethylheptane-dionate
CAS编号15492-50-9
产品熔点191-193ºC
产品沸点250ºC (subl. 183ºC/1.3mm)
产品闪点67.2ºC
精确质量704.35900
PSA102.42000
LogP7.82070
外观性状淡黄色晶体
蒸气压0.287mmHg at 25°C
稳定性

常温常压下稳定

避免的物料: 氧化物
储存条件

常温密闭避光,通风干燥

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安全声明 (欧洲) S22-S24/25

Section 1: Product Identification
Chemical Name:Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)samarium (III) (99.9%-Sm) (REO) Sm(TMHD)3
CAS Registry Number:15492-50-9
Formula:Sm(C11H19O2)3
EINECS Number:none
Chemical Family:metal beta-diketonate complexes
Synonym:Dipivaloylmethane, samarium complex

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound15492-50-9100%no datano data

Section 3: Hazards Identification
Emergency Overview:No particular hazard associated with this material.
Primary Routes of Exposure:Ingestion
Eye Contact:May cause slight to mild irritation of the eyes.
Skin Contact:May cause slight to mild irritation of the skin.
Inhalation:(If dust) May be irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No information on the physiological effects of ingestion.
Acute Health Affects:May be irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with soap and water. Remove contaminated clothes if necessary. Seek medical
Skin Exposure:
assistance if irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion:Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious).

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, dry powder or foam
If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
Special Fire Fighting Procedures:
breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store in a sealed container. Keep away from heat and moisture.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear appropriate chemical resistant gloves and protective clothing.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
Respirator:
requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:pale yellow xtl.
Molecular Weight:700.11
Melting Point:191-193
Boiling Point:dec.183° subl.183°/1.3mm
Vapor Pressure:subl. 183°C/1.3mm
Specific Gravity:no data
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable solid
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:halogens and oxidizing agents
Decomposition Products:Carbon dioxide, carbon monoxide, organic vapors, and metal oxides and carbonates.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:No data available
Mutagenic Effects:No data available
Tetratogenic Effects:No data available

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

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