环辛酮肟 ,Cyclooctanone oxime ,≥98.0%

产品编号:Bellancom-B235042| CAS NO:1074-51-7| 分子式:C8H15NO| 分子量:141.2108

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货号 包装 价格 库存与货期 购买量 操作
Bellancom-B235042
1356.00 杭州 北京(现货)
Bellancom-B235042
288.00 杭州 北京(现货)
Bellancom-B235042
1012.00 杭州 北京(现货)

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产品名称 环辛酮肟
英文名称Cyclooctanone oxime
CAS编号1074-51-7
产品熔点36-37ºC
产品沸点128-129ºC (14 torr)
产品密度1.04g/cm3
产品闪点128-129°C/14mm
精确质量141.11500
PSA32.59000
LogP2.56090
蒸气压0.00671mmHg at 25°C
折射率1.517
稳定性

常温常压下稳定,避免氧化物接触

储存条件

保持容器密封,储存在阴凉,干燥的地方

相关文档

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风险声明 (欧洲) 20/21/22
安全声明 (欧洲) S24/25
危险品运输编码 UN 2811
WGK德国 3
海关编码 2928000090
Name: Cyclooctanone Oxime 98% Material Safety Data Sheet
Synonym: None Known
CAS: 1074-51-7
Section 1 - Chemical Product MSDS Name:Cyclooctanone Oxime 98% Material Safety Data Sheet
Synonym:None Known

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
1074-51-7 Cyclooctanone Oxime 98% unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing.
Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 1074-51-7: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 128-129 deg C@14 mmHg
Freezing/Melting Point: 36-37 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C8H15NO
Molecular Weight: 141.21

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Hydrogen cyanide, carbon monoxide, oxides of nitrogen, carbon dioxide, nitric acid.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 1074-51-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Cyclooctanone Oxime - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 1074-51-7: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 1074-51-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1074-51-7 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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文献:Ballini, Roberto; Barboni, Luciano; Filippone, Paolino Chemistry Letters, 1997 , # 5 p. 475 - 476

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文献:Hirabayashi, Tomotaka; Sakaguchi, Satoshi; Ishii, Yasutaka Angewandte Chemie - International Edition, 2004 , vol. 43, # 9 p. 1120 - 1123

~10%

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文献:Ishii, Yasutaka; Nakano, Tatsuya; Iwahama, Takahiro Patent: US2003/171618 A1, 2003 ;

~64%

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文献:Suzuki, Ken; Watanabe, Tomonari; Murahashi, Shun-Ichi Journal of Organic Chemistry, 2013 , vol. 78, # 6 p. 2301 - 2310

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文献:Applied Catalysis A: General, , vol. 378, # 1 p. 33 - 41

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文献:Journal fuer Praktische Chemie (Leipzig), , vol. 33, p. 282 - 292

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文献:Journal fuer Praktische Chemie (Leipzig), , vol. 33, p. 282 - 292

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文献:Advanced Synthesis and Catalysis, , vol. 354, # 8 p. 1413 - 1416

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文献:Chemische Berichte, , vol. 90, p. 1188,1199

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